The chemistry of phosphinous amides (aminophosphanes):: Old reagents with new applications

被引:0
作者
Alajarín, M [1 ]
López-Leonardo, C [1 ]
Llamas-Lorente, P [1 ]
机构
[1] Univ Murcia, Fac Quim, Dept Quim Organ, E-30100 Murcia, Spain
来源
NEW ASPECTS IN PHOSPHORUS CHEMISTRY V | 2005年 / 250卷
关键词
phosphinous amides; aminophosphanes; phosphanamines; catalysis;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This chapter is devoted to phosphinous amides, a particular class of tervalent aminophosphanes. First, attention is focused on their stability and synthetic procedures. Reports dealing with their prototropic equilibrium and main group chemistry are also considered. Last but not least the really important applications of these species as metal ligands in the field of catalysis are reviewed, including asymmetric variants.
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页码:77 / 106
页数:30
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