Structural and mechanical properties of Cr-Zr-N coatings with different Zr content

被引:19
作者
Aissani, Linda [1 ,2 ]
Fellah, Mamoun [2 ,3 ]
Nouveau, Corinne [4 ]
Samad, Mohammed Abdul [5 ]
Montagne, Alex [6 ]
Iost, Alain [6 ]
机构
[1] ABBES Laghrour Khenchela Univ, Phys Dept, BO 1251, Khenchela 40004, Algeria
[2] Annaba Univ, Lab Foundry, Tribol Mat Surface & Interfaces Grp, BO 12, Annaba 23000, Algeria
[3] ABBES Laghrour Khenchela Univ, Mech Engn Dept, Khenchela, Algeria
[4] King Fahd Univ Petr & Minerals, Mech Engn Dept, LaBoMaP, ENSAM, Rue Porte Paris, Cluny, France
[5] King Fahd Univ Petr & Minerals, Mech Engn Dept, Dhahran, Saudi Arabia
[6] ENSAM Arts & Metiers Paris Tech, Mech Surfaces & Mat Proc Lab, 8 Blvd Louis XIV, Lille, France
关键词
CrN; ZrN; Cr-Zr-N; wear; friction; nanoindentation; TRIBOLOGICAL PROPERTIES; OXIDATION RESISTANCE; ZIRCONIUM NITRIDE; THIN-FILMS; AL-N; MICROSTRUCTURE; ADHESION; BEHAVIOR; NICKEL; TIN;
D O I
10.1080/02670844.2017.1338378
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Cr-Zr-N films have been synthesised using R.F reactive magnetron sputtering system on Si (100) wafer and XC100 steel substrate without heating. The structural, mechanical and friction coefficient evolution as a function of the Zr content were investigated by XRD, (EDS, WDS), WPS, XPS, SEM, AFM, nanoindentation, Scratch adhesion and pin-on-disc sliding wear tests. The results show, that, with increasing Zr content, the film structure changed with the coexistence of (Cr-N, Zr-N) crystallographic orientation mixture. The films formed a (Cr, Zr) N solid solution where Zr atoms substitute Cr atoms. CrN lattice parameter increased from 4.17 to 4.32 angstrom with the crystallite size refinement. The mechanical parameters (H, sigma, E, H/E and H-3/E-2) were significantly improved in comparison to binary films, especially at 29 at.-% Zr. The friction and wear behaviour of the Cr-Zr (29 at.-% Zr)-N coating also showed a significant improvement.
引用
收藏
页码:69 / 77
页数:9
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