Photovoltaic characteristics of p-β-FeSi2(Al)/n-Si(100) heterojunction solar cells and the effects of interfacial engineering

被引:53
作者
Dalapati, G. K. [1 ]
Liew, S. L. [1 ]
Wong, A. S. W. [1 ]
Chai, Y. [1 ]
Chiam, S. Y. [1 ]
Chi, D. Z. [1 ]
机构
[1] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
BETA-FESI2;
D O I
10.1063/1.3536523
中图分类号
O59 [应用物理学];
学科分类号
摘要
Heterojunction solar cells with Al-alloyed polycrystalline p-type beta-phase iron disilicide [p-beta-FeSi2(Al)] on n-Si(100) were investigated. The p-beta-FeSi2(Al) was grown by sputter deposition and rapid-thermal annealing. Photocurrent of similar to 1.8 mA/cm(2) and open-circuit voltage of similar to 63 mV were obtained for p-beta-FeSi2(Al)/n-Si(100)/Ti/Al control cells with indium-tin-oxide (ITO) top electrode. Open-circuit voltage increased considerably once thin Al layer was deposited before amorphous-FeSi2(Al) deposition. Furthermore, device performances were found to improve significantly (similar to 5.3 mA/cm(2) and similar to 450 mV) by introducing germanium-nitride electron-blocking layer between ITO and p-beta-FeSi2(Al). The improvement is attributed to the formation of epitaxial Al-containing p(+)-Si at p-beta-FeSi2(Al)/n-Si(100) interface and suppressed back-diffusion of photogenerated electrons into ITO. (C) 2011 American Institute of Physics. [doi:10.1063/1.3536523]
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页数:3
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