Helical poly(isocyanides): past, present and future

被引：214
作者：
Schwartz, Erik [1 ]
Koepf, Matthieu [1 ]
Kitto, Heather J. [1 ]
Nolte, Roeland J. M. [1 ]
Rowan, Alan E. [1 ]
机构：
[1] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands
来源：
POLYMER CHEMISTRY | 2011年 / 2卷 / 01期
关键词：
SENSE SELECTIVE POLYMERIZATION; COUPLED CIRCULAR-DICHROISM; BULKY ARYL ISOCYANIDE; MACROMOLECULAR HELICITY; SCREW-SENSE; POLY(4-CARBOXYPHENYL ISOCYANIDE); NANOSCALE ARCHITECTURE; LIVING POLYMERIZATION; FORCE MICROSCOPY; CHIRAL AMINES;
D O I：
10.1039/c0py00246a
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Stable helical polymers with a preferred handedness are compounds that offer intriguing characteristics. This review describes the progress in the synthesis of helical polyisocyanides and the investigations to determine their structural properties, such as helical pitch and handedness, by spectroscopic measurements and high resolution AFM. This review is not intended to be comprehensive; its purpose is to highlight recent studies that allow a better understanding of the main aspects of helical polyisocyanides.
引用
收藏
页码：33 / 47
页数：15
相关论文
共 136 条
[1]   Long-range chiral induction in chemical systems with helical organization. Promesogenic monomers in the formation of poly(isocyanide)s and in the organization of liquid crystals [J].
Amabilino, DB ;
Ramos, E ;
Serrano, JL ;
Sierra, T ;
Veciana, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (36) :9126-9134
[2]   Reversible and irreversible conformational changes in poly(isocyanide)s: a remote stereoelectronic effect [J].
Amabilino, DB ;
Serrano, JL ;
Veciana, J .
CHEMICAL COMMUNICATIONS, 2005, (03) :322-324
[3]   Chiral teleinduction in the polymerization of isocyanides [J].
Amabilino, DB ;
Ramos, E ;
Serrano, JL ;
Sierra, T ;
Veciana, J .
POLYMER, 2005, 46 (05) :1507-1521
[4]  
Amabilino DB, 1998, ADV MATER, V10, P1001, DOI 10.1002/(SICI)1521-4095(199809)10:13<1001::AID-ADMA1001>3.3.CO
[5]  
2-P
[6]  
[Anonymous], 1859, ANN CHEM PHARM, DOI DOI 10.1002/JLAC.18591120307
[7]  
[Anonymous], FOLDAMERS
[8]  
[Anonymous], 2000, Circular Dichroism: Principles and Applications
[9]   Vibrational self-trapping in beta-sheet structures observed with femtosecond nonlinear infrared spectroscopy [J].
Bodis, Pavol ;
Schwartz, Erik ;
Koepf, Matthieu ;
Cornelissen, Jeroen J. L. M. ;
Rowan, Alan E. ;
Nolte, Roeland J. M. ;
Woutersen, Sander .
JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (12)
[10]   PREPARATION AND REACTIONS OF (FORMAMIDOMETHYL)AMINES, (FORMANIDOMETHYL)SULFIDES, AND (FORMANIDOMETHYL)SULFONES [J].
BOHME, H ;
FUCHS, G .
CHEMISCHE BERICHTE-RECUEIL, 1970, 103 (09) :2775-&
12345678910