Recyclable Perovskite as Heterogeneous Photocatalyst for Aminomethylation of Imidazo-Fused Heterocycles

被引：76

作者：

Shi, Tao ^{[1
]}

Sun, Kai ^{[1
]}

Chen, Xiao-Lan ^{[1
]}

Zhang, Zhao-Xin ^{[1
]}

Huang, Xian-Qiang ^{[2
]}

Peng, Yu-Yu ^{[3
]}

Qu, Ling-Bo ^{[1
]}

Yu, Bing ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450001, Peoples R China

[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China

[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 11期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Perovskites; Photocatalysis; Decarboxylative coupling; Heterogeneous catalysis; LIGHT PHOTOREDOX CATALYSIS; C-H ACTIVATION; SULFONES; ALCOHOLS; ACIDS;

D O I：

10.1002/adsc.201901324

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A sustainable and cost-effective protocol for direct aminomethylation of imidazo-fused heterocycles by decarboxylative coupling reaction of N-phenylglycines with imidazo-fused heterocycles in the presence of CsPbBr3 under the irradiation of visible light has been developed. This is the first example of CsPbBr3-catalyzed aminomethylation of imidazo-fused heterocycles. The eminent advantage of this work is in that, CsPbBr3 is easily prepared and can be used at least 5 times without obvious reduction in its activity, exhibiting high catalyst economic feature.

引用

页码：2143 / 2149

页数：7

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