Recyclable Perovskite as Heterogeneous Photocatalyst for Aminomethylation of Imidazo-Fused Heterocycles

被引：76

作者：

Shi, Tao ^{[1
]}

Sun, Kai ^{[1
]}

Chen, Xiao-Lan ^{[1
]}

Zhang, Zhao-Xin ^{[1
]}

Huang, Xian-Qiang ^{[2
]}

Peng, Yu-Yu ^{[3
]}

Qu, Ling-Bo ^{[1
]}

Yu, Bing ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450001, Peoples R China

[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China

[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 11期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Perovskites; Photocatalysis; Decarboxylative coupling; Heterogeneous catalysis; LIGHT PHOTOREDOX CATALYSIS; C-H ACTIVATION; SULFONES; ALCOHOLS; ACIDS;

D O I：

10.1002/adsc.201901324

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A sustainable and cost-effective protocol for direct aminomethylation of imidazo-fused heterocycles by decarboxylative coupling reaction of N-phenylglycines with imidazo-fused heterocycles in the presence of CsPbBr3 under the irradiation of visible light has been developed. This is the first example of CsPbBr3-catalyzed aminomethylation of imidazo-fused heterocycles. The eminent advantage of this work is in that, CsPbBr3 is easily prepared and can be used at least 5 times without obvious reduction in its activity, exhibiting high catalyst economic feature.

引用

页码：2143 / 2149

页数：7

共 72 条

[1]

Albini A., 2010, Handbook of synthetic photochemistry

[2] Heterogeneous Visible-Light Photoredox Catalysis with Graphitic Carbon Nitride for α-Aminoalkyl Radical Additions, Allylations, and Heteroarylations [J].

Cai, Yunfei ;

Tang, Yurong ;

Fan, Lulu ;

Lefebvre, Quentin ;

Hou, Hong ;

Rueping, Magnus .

ACS CATALYSIS, 2018, 8 (10) :9471-+

[3] Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [J].

Capaldo, Luca ;

Ravelli, Davide .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (15) :2056-2071

[4] Exploration of Visible-Light Photocatalysis in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond [J].

Chen, Jia-Rong ;

Hu, Xiao-Qiang ;

Lu, Liang-Qiu ;

Xiao, Wen-Jing .

ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (09) :1911-1923

[5] Lead-Free Cs3Bi2Br9 Perovskite as Photocatalyst for Ring-Opening Reactions of Epoxides [J].

Dai, Yitao ;

Tuysuz, Harun .

CHEMSUSCHEM, 2019, 12 (12) :2587-2592

[6] Nitrogen vacancy engineered graphitic C3N4-based polymers for photocatalytic oxidation of aromatic alcohols to aldehydes [J].

Ding, Jing ;

Xu, Wei ;

Wan, Hui ;

Yuan, Dashui ;

Chen, Chong ;

Wang, Lei ;

Guan, Guofeng ;

Dai, Wei-Lin .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 221 :626-634

[7] Merging Visible Light Photoredox Catalysis with Metal Catalyzed C-H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants [J].

Fabry, David C. ;

Rueping, Magnus .

ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (09) :1969-1979

[8] Discovery of Imidazopyridine Derivatives as Highly Potent Respiratory Syncytial Virus Fusion Inhibitors [J].

Feng, Song ;

Hong, Di ;

Wang, Baoxia ;

Zheng, Xiufang ;

Miao, Kun ;

Wang, Lisha ;

Yun, Hongying ;

Gao, Lu ;

Zhao, Shuhai ;

Shen, Hong C. .

ACS MEDICINAL CHEMISTRY LETTERS, 2015, 6 (03) :359-362

[9] Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide [J].

Fu, Ming-Chen ;

Shang, Rui ;

Zhao, Bin ;

Wang, Bing ;

Fu, Yao .

SCIENCE, 2019, 363 (6434) :1429-+

[10] Visible Light-Induced Thiocyanation of Enaminone C-H Bond to Access Polyfunctionalized Alkenes and Thiocyano Chromones [J].

Gao, Yong ;

Liu, Yunyun ;

Wan, Jie-Ping .

JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (04) :2243-2251

← 1 2 3 4 5 6 7 8 →