High-Temperature Oxidation Behavior of Refractory High-Entropy Alloys: Effect of Alloy Composition

被引：174

作者：

Gorr, Bronislava ^{[1
]}

Mueller, Franz ^{[1
]}

Azim, Maria ^{[1
]}

Christ, Hans-Juergen ^{[1
]}

Mueller, Torsten ^{[2
]}

Chen, Hans ^{[3
]}

Kauffmann, Alexander ^{[3
]}

Heilmaier, Martin ^{[3
]}

机构：

[1] Univ Siegen, Inst Werkstofftech, Paul Bonatz Str 9-11, D-57068 Siegen, Germany

[2] Inst Bau & Werkstoffchem, Paul Bonatz Str 9-11, D-57068 Siegen, Germany

[3] Karlsruhe Inst Technol, Inst Angewandte Mat Werkstoffkunde, Engelbert Arnold Str 4, D-76131 Karlsruhe, Germany

来源：

OXIDATION OF METALS | 2017年 / 88卷 / 3-4期

关键词：

High-entropy alloys; Refractory metals; Oxidation kinetics; Oxide scale morphology; Oxide evaporation; PHASE-EQUILIBRIA; MICROSTRUCTURE; SOLUBILITY;

D O I：

10.1007/s11085-016-9696-y

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The high-temperature oxidation behavior of a new family of refractory high-entropy alloys (HEAs) with compositions of W-Mo-Cr-Ti-Al, Nb-Mo-Cr-Ti-Al and Ta-Mo-Cr-Ti-Al was studied at 1000 and 1100 A degrees C. Based on these equimolar starting compositions, the main incentive of this study was to select the most promising alloy system whose properties may then be successively improved. Despite the high amount of refractory elements, Ta-Mo-Cr-Ti-Al showed good oxidation resistance at 1000 and 1100 A degrees C. Moderate values of mass gain and complex oxidation kinetics were observed for the W- and Nb-containing HEAs. These alloys formed inhomogeneous oxide scales possessing regions with thick and porous layers as well as areas revealing quite thin oxide scales due to the formation of discontinuous Cr- and Al-rich scales. The most promising behavior was shown by the alloy Ta-Mo-Cr-Ti-Al which followed the parabolic rate law for oxide growth due to the formation of a thin and compact Al-rich layer.

引用

页码：339 / 349

页数：11

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