Pyrolysis Product Evolution Characteristics of Bio-Ferment Residue Using Thermogravimetric Analysis, Fourier Transform Infrared Spectroscopy, and Mass Spectrometry

被引：10

作者：

Du, Y. ^{[1
]}

Jiang, X. ^{[1
]}

Ma, X. ^{[2
]}

Liu, X. ^{[3
]}

Lv, G. ^{[1
]}

Jin, Y. ^{[1
]}

Wang, F. ^{[1
]}

Chi, Y. ^{[1
]}

Yan, J. ^{[1
]}

机构：

[1] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China

[2] Zhejiang Univ, Ind Technol Res Inst, Hangzhou 310003, Zhejiang, Peoples R China

[3] Zhejiang Jinhua Conba Biopharm Co Ltd, Jinhua, Zhejiang, Peoples R China

来源：

JOURNAL OF APPLIED SPECTROSCOPY | 2015年 / 81卷 / 06期

基金：

国家高技术研究发展计划(863计划);

关键词：

waste; pyrolysis; thermogravimetric analysis; Fourier transform infrared spectroscopy; mass spectrometry; COAL; CELLULOSE; NH3; HCN;

D O I：

10.1007/s10812-015-0054-7

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Bio-ferment residues (BR) are wastes produced by a biological fermentation process for the production of antibiotics. In this work, the evolution characteristics of pyrolysis products of BR were studied using TG-FTIR analysis and MS analysis. It was found that species such as H2O, NH3, CH4, carboxylic acid, aldehydes, alkanes, HCN, HNCO, CO, and CO2 were released at a temperature lower than 600A degrees C. Above 600A degrees C, the dominant products were H-2, CO, and CO2. Scarcely any acetylene or benzene was observed. HCN and HNCO were found to evolve in a small amount, while other potential pollutants such as H2S, COS, and CS2 were hardly detected.

引用

页码：1073 / 1077

页数：5

共 16 条

[1] Pyrolysis of blends of coal and tyre wastes in a fixed bed reactor and a rotary oven [J].

Acevedo, B. ;

Barriocanal, C. ;

Alvarez, R. .

FUEL, 2013, 113 :817-825

[2] Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems [J].

Balat, Mustafa ;

Balat, Mehmet ;

Kirtay, Elif ;

Balat, Havva .

ENERGY CONVERSION AND MANAGEMENT, 2009, 50 (12) :3147-3157

[3] TG-FTIR analysis of biomass pyrolysis [J].

Bassilakis, R ;

Carangelo, RM ;

Wójtowicz, MA .

FUEL, 2001, 80 (12) :1765-1786

[4] Review of fast pyrolysis of biomass and product upgrading [J].

Bridgwater, A. V. .

BIOMASS & BIOENERGY, 2012, 38 :68-94

[5] Evaluation of Cofiring Bioferment Residue with Coal at Different Proportions: Combustion Characteristics and Kinetics [J].

Du, Yuying ;

Jiang, Xuguang ;

Ma, Xiaojun ;

Liu, Xudong ;

Lv, Guojun ;

Jin, Yuqi ;

Wang, Fei ;

Chi, Yong ;

Yan, Jianhua .

ENERGY & FUELS, 2013, 27 (10) :6295-6303

[6] Quantitative and kinetic TG-FTIR study of biomass residue pyrolysis: Dry distiller's grains with solubles (DDGS) and chicken manure [J].

Giuntoli, J. ;

de Jong, W. ;

Arvelakis, S. ;

Spliethoff, H. ;

Verkooijen, A. H. M. .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2009, 85 (1-2) :301-312

[7] Formation of HNCO, HCN, and NH3 from the pyrolysis of bark and nitrogen-containing model compounds [J].

Hansson, KM ;

Samuelsson, J ;

Tullin, C ;

Åmand, LE .

COMBUSTION AND FLAME, 2004, 137 (03) :265-277

[8] Pyrolysis of poly-L-leucine under combustion-like conditions [J].

Hansson, KM ;

Åmand, LE ;

Habermann, A ;

Winter, F .

FUEL, 2003, 82 (06) :653-660

[9] A correlation for calculating HHV from proximate analysis of solid fuels [J].

Parikh, J ;

Channiwala, SA ;

Ghosal, GK .

FUEL, 2005, 84 (05) :487-494

[10] TG-FTIR study on co-pyrolysis of municipal solid waste with biomass [J].

Ren, Qiangqiang ;

Zhao, Changsui ;

Wu, Xin ;

Liang, Cai ;

Chen, Xiaoping ;

Shen, Jiezhong ;

Tang, Guoyong ;

Wang, Zheng .

BIORESOURCE TECHNOLOGY, 2009, 100 (17) :4054-4057

← 1 2 →