Synthesis of decamethyltitanocene alkyne complexes and molecular structure of the diphenylacetylene complex Cp2*Ti(η2-PhC2Ph)

被引：6
作者：
Arndt, Perdita
Burlakov, Vladimir V.
Spannenberg, Anke
Rosenthal, Uwe
机构：
[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
titanocene; diphenylacetylene; X-ray crystal structure;
D O I：
10.1016/j.inoche.2007.03.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Stable complexes Cp-2*Ti(eta(2)-RC CR) (R = Ph (2) Et (7)) were obtained in high yield by the reduction of Cp-2*TiCl2 with magnesium in the presence of the corresponding alkyne, whereas the structure of Cp-2*Ti(PhC CPh) (2) was confirmed by X-ray studies for the first time. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：792 / 794
页数：3
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