Mizoroki-Heck Reaction of (1-Fluorovinyl)methyldiphenylsilane with Aryl Iodides

被引：14
|
作者：
Hirotaki, Kensuke [1 ]
Hanamoto, Takeshi [1 ]
机构：
[1] Saga Univ, Dept Chem & Appl Chem, Saga 8408502, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 20期
关键词：
PALLADIUM-CATALYZED ARYLATION; HALIDES; VINYLATION;
D O I：
10.1021/jo201720x
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Mizoroki-Heck reaction of (1-fluorovinyl)methyldiphenylsilane with a variety of aryl iodides was accomplished under the conditions composing Pd(OAc)(2), Ag2CO3 and MS 4 A in 1,4-dioxane to give the corresponding (E)-beta-aryl-(alpha-fluorovinyl)methyldiphenylsilanes with excellent stereoselectivity.
引用
收藏
页码：8564 / 8568
页数：5
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