Merging New Organoborane Chemistry with Living Radical Polymerization

被引：10
|
作者：
Corrigan, Nathaniel [1 ,2 ]
Jung, Kenward [1 ,2 ]
Boyer, Cyrille [1 ,2 ]
机构：
[1] Univ New South Wales, Sch Chem Engn, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia
[2] Univ New South Wales, Sch Chem Engn, Ctr NanoMed, Sydney, NSW 2052, Australia
来源：
CHEM | 2020年 / 6卷 / 06期
关键词：
RAFT;
D O I：
10.1016/j.chempr.2020.05.021
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this issue of Cell Reports Physical Science, Pan and co-workers synthesize alkylcatecholboranes that can be oxidized by oxygen to drive the release of carbon-centered radicals for initiating reversible addition-fragmentation chain transfer (RAFT) polymerization. These organoboranes can slowly decompose to radicals that enable RAFT polymerization with exceptional control yielding ultra-high molecular weight (UHMW) polymers.
引用
收藏
页码：1212 / 1214
页数：3
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