Merging New Organoborane Chemistry with Living Radical Polymerization

被引：10

作者：

Corrigan, Nathaniel ^{[1
,2
]}

Jung, Kenward ^{[1
,2
]}

Boyer, Cyrille ^{[1
,2
]}

机构：

[1] Univ New South Wales, Sch Chem Engn, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

[2] Univ New South Wales, Sch Chem Engn, Ctr NanoMed, Sydney, NSW 2052, Australia

来源：

CHEM | 2020年 / 6卷 / 06期

关键词：

RAFT;

D O I：

10.1016/j.chempr.2020.05.021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this issue of Cell Reports Physical Science, Pan and co-workers synthesize alkylcatecholboranes that can be oxidized by oxygen to drive the release of carbon-centered radicals for initiating reversible addition-fragmentation chain transfer (RAFT) polymerization. These organoboranes can slowly decompose to radicals that enable RAFT polymerization with exceptional control yielding ultra-high molecular weight (UHMW) polymers.

引用

页码：1212 / 1214

页数：3

共 11 条

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