Metal catalyzed multicomponent syntheses of secondary propargylamides and oxazoles from silylimines, acid chlorides, and alkynes

被引：33

作者：

Black, DA ^{[1
]}

Arndtsen, BA ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

TETRAHEDRON | 2005年 / 61卷 / 48期

基金：

加拿大自然科学与工程研究理事会;

关键词：

alkynes; oxazoles; multicomponent;

D O I：

10.1016/j.tet.2005.09.096

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper(I) and zinc(II) catalyzed routes to construct secondary propargylamides in one-pot procedures from aldehydes, LiN(TMS)(2), acid chlorides, and alkynes are described. This reaction has been subsequently used to provide a one-pot synthesis of oxazoles from four simple building blocks. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：11317 / 11321

页数：5

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