Recent advances in chiral phosphine-silver(I) complex-catalyzed asymmetric reactions

被引：54

作者：

Yanagisawa, Akira ^{[1
]}

Arai, Takayoshi ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Sci, Dept Chem, Chiba 2638522, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 10期

关键词：

D O I：

10.1039/b717104h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Since the first report of silver(I)-catalyzed asymmetric aldol-type reaction of activated isocyanides with aldehydes using a chiral ferrocenylphosphine as a chiral phosphine ligand has been appeared in 1990, various chiral phosphine-silver(i) catalysts have been utilized in asymmetric transformations. This feature articles describes recent examples of chiral phosphine-silver(i) complex-catalyzed asymmetric reactions such as allylation, aldol reaction, Mannich-type reaction, hetero-Diels-Alder reaction, 1,3-dipolar cycloaddition and nitroso aldol reaction.

引用

页码：1165 / 1172

页数：8

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