Recent advances in chiral phosphine-silver(I) complex-catalyzed asymmetric reactions

被引：55
|
作者：
Yanagisawa, Akira [1 ]
Arai, Takayoshi [1 ]
机构：
[1] Chiba Univ, Grad Sch Sci, Dept Chem, Chiba 2638522, Japan
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 10期
关键词：
D O I：
10.1039/b717104h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Since the first report of silver(I)-catalyzed asymmetric aldol-type reaction of activated isocyanides with aldehydes using a chiral ferrocenylphosphine as a chiral phosphine ligand has been appeared in 1990, various chiral phosphine-silver(i) catalysts have been utilized in asymmetric transformations. This feature articles describes recent examples of chiral phosphine-silver(i) complex-catalyzed asymmetric reactions such as allylation, aldol reaction, Mannich-type reaction, hetero-Diels-Alder reaction, 1,3-dipolar cycloaddition and nitroso aldol reaction.
引用
收藏
页码：1165 / 1172
页数：8
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