Giant field dependence of the low temperature relaxation of the magnetization in a dysprosium(III)-DOTA complex

被引：200

作者：

Car, Pierre-Emmanuel

Perfetti, Mauro

Mannini, Matteo

Favre, Annaick

Caneschi, Andrea

Sessoli, Roberta ^{[1
]}

机构：

[1] Univ Florence, Dept Chem Ugo Schiff, I-50019 Sesto, Fiorentino, Italy

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 13期

关键词：

SINGLE-MOLECULE-MAGNET; LANTHANIDE; BEHAVIOR; DOTA;

D O I：

10.1039/c0cc05850e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The square antiprismatic Na[Dy(DOTA)(H2O)]center dot 4H(2)O complex was characterised by single crystal X-ray diffraction and ac magnetic susceptometry. Two competing mechanisms for magnetic relaxation as well as the remarkable increase of six orders of magnitude in the relaxation time upon application of a static magnetic field were detected.

引用

收藏

页码：3751 / 3753

页数：3

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