Basolites: A type of Metal Organic Frameworks highly efficient in the one-pot synthesis of quinoxalines from α-hydroxy ketones under aerobic conditions

被引：12

作者：

Godino-Ojer, Marina ^{[1
,2
]}

Shamzhy, Mariya ^{[3
]}

Cejka, Jiri ^{[3
]}

Perez-Mayoral, Elena ^{[1
]}

机构：

[1] Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan & Quim Tecn, Paseo Senda Rey 9, E-28040 Madrid, Spain

[2] UFV, Fac Ciencias Expt, Ctra Pozuelo Majadahonda Km 1-800, Madrid 28223, Spain

[3] Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Hlavova 8, Prague 2, Czech Republic

来源：

CATALYSIS TODAY | 2020年 / 345卷

关键词：

Basolites; Metal-Organic-Frameworks; Nanocatalysts; Fine chemicals; Quinoxalines; HETEROGENEOUS CATALYSTS; OXIDATIVE CYCLIZATION; GREEN SYNTHESIS; ACID; CU-3(BTC)(2); ADSORPTION; QUINOLINES; ZEOLITES; BTC; CU;

D O I：

10.1016/j.cattod.2019.08.002

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

We report here efficient synthesis of quinoxalines from o-phenylendiamine and alpha-hydroxy ketones over commercial Basolites. The concentration and type of acid centres, as CUS sites, together with the porosity of the samples strongly influence the resulting conversion and selectivity. Our results indicate that the formation of quinoxalines preferentially follows a new route, in which tautomerization reactions are also involved.

引用

页码：258 / 266

页数：9

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