Preparation and characterization of hyperbranched poly(ether ether ketone)s suitable as rheology control agents for linear poly(ether ether ketone)s

被引：11

作者：

Li, Xiujie ^{[1
]}

Zhang, Shuling ^{[1
]}

Zhou, Fugui ^{[1
]}

Pang, Jinhui ^{[1
]}

Zhang, Chunfeng ^{[1
]}

Sun, Dong ^{[1
]}

Mu, Jianxin ^{[1
]}

Wang, Guibin ^{[1
]}

Jiang, Zhenhua ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Alan G MacDiarmid Inst, Changchun 130012, Peoples R China

来源：

MACROMOLECULAR RESEARCH | 2011年 / 19卷 / 05期

关键词：

A(2) + BB '(2) strategy; hyperbranched; poly(ether ketones); rheology; synthesis; BB'(2) TYPE MONOMERS; ONE-STEP SYNTHESIS; POLYMERIZATION; POLYMERS; POLYADDITION; A(2);

D O I：

10.1007/s13233-011-0503-y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hyperbranched poly(ether ether ketone)s (HPEEKs) that were suitable as rheology control agents for linear poly(ether ether ketone)s (LPEEKs) were first prepared via commercially available hydroquinone (A(2) monomer, HQ) and synthesized 3,4',5-trifluoro-benzophenone (BB'(2) monomer, TF) effortlessly. The polymerization mode of A(2) + BB'(2) was demonstrated by MS. Moreover, FTIR, (1)H NMR, (13)C NMR, and (19)F NMR spectroscopy revealed the structure and degree of branching (DB) of the resulting polymers. In comparison with A(2) + B(3) approach, HPEEK prepared using an A(2) + BB'(2) strategy possessed a higher molecular weight, and improved the melt processability of LPEEK. Remarkably, with the addition of HPEEK, the mechanical properties of LPEEK increased with a HPEEK content of 5%. The improved mechanical properties were attributed to the good miscibility. Moreover, the addition of HPEEK did not decrease the thermal stability of LPEEK.

引用

页码：427 / 435

页数：9

共 27 条

[1] [Anonymous], 1988, POLYMER, DOI DOI 10.1021/AR900158P
[2] A modular approach toward functionalized three-dimensional macromolecules:: From synthetic concepts to practical applications
Bosman, AW
Vestberg, R
Heumann, A
Fréchet, JMJ
Hawker, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (03) : 715 - 728
[3] DEBRABANDERVAND.EM, 1993, ANGEW CHEM INT EDIT, V32, P1306
[4] An A2+B3 approach to hyperbranched aliphatic polyethers containing chain end epoxy substituents
Emrick, T
Chang, HT
Fréchet, JMJ
[J]. MACROMOLECULES, 1999, 32 (19) : 6380 - 6382
[5] MOLECULAR SIZE DISTRIBUTION IN THREE DIMENSIONAL POLYMERS .6. BRANCHED POLYMERS CONTAINING A-R-BF-1 TYPE UNITS
FLORY, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (11) : 2718 - 2723
[6] FRCHET JMJ, 1995, SCIENCE, V269, P1080
[7] FRCHET JMJ, 1994, SCIENCE, V263, P1710
[8] FRCHET JMJ, 1996, MACROMOL SCI PURE A, V33, P1399
[9] Polyaddition of B2 and BB′2 type monomers to A2 type monomer.: 1.: Synthesis of highly branched copoly(sulfone-amine)s
Gao, C
Yan, DY
[J]. MACROMOLECULES, 2001, 34 (02) : 156 - 161
[10] Postsynthetic modification at the focal point of a hyperbranched polymer
Gittins, PJ
Twyman, LJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (06) : 1646 - 1647

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