Diethylamine-Catalyzed Dimerization of Thiols: An Inexpensive and Green Method for the Synthesis of Homodisulfides Under Aqueous Conditions

被引：9
作者：
Abaee, M. Saeed [1 ]
Mojtahedi, Mohammad M. [1 ]
Navidipoor, Somayeh [1 ]
机构：
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
来源：
SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 02期
关键词：
Aqueous conditions; disulfides; oxidation; thiols; SOLVENT-FREE CONDITIONS; OXIDATIVE TRANSFORMATION; SYMMETRICAL DISULFIDES; AIR OXIDATION; EFFICIENT; SULFIDES; EPOXIDES; RECEPTOR; REAGENT; WATER;
D O I：
10.1080/00397910903531904
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Under H2O / Et2NH / atmospheric oxygen conditions, thiols are converted to their respective homodisulfides within a few hours. The process is conducted at room temperature for quantitative dimerization of aromatic, benzylic, and aliphatic thiols without the use of any extra additive.
引用
收藏
页码：170 / 176
页数：7
相关论文
共 36 条
[1]   Ultrasound promoted aminolysis of epoxides in aqueous media:: A rapid procedure with no pH adjustment for additive-free synthesis of β-aminoalcohols [J].
Abaee, M. Saeed ;
Hamidi, Vahid ;
Mojtahedi, Mohammad M. .
ULTRASONICS SONOCHEMISTRY, 2008, 15 (05) :823-827
[2]   Additive-free thiolysis of epoxides in water:: A green and efficient regioselective pathway to β-hydroxy sulfides [J].
Abaee, M. Saeed ;
Mojtahedi, Mohammad M. ;
Abbasi, Hassan ;
Fatemi, Ensieh R. .
SYNTHETIC COMMUNICATIONS, 2008, 38 (02) :282-289
[3]   Synthesis of cyclic mono- and bis-disulfides and their selective conversion to mono- and bis-thiosulfinates [J].
Bourles, Emilie ;
de Sousa, Rodolphe Alves ;
Galardon, Erwan ;
Selkti, Mohamed ;
Tomas, Alain ;
Artaud, Isabelle .
TETRAHEDRON, 2007, 63 (11) :2466-2471
[4]  
Cremlyn RJ., 1996, An introduction to organosulfur chemistry
[5]   A new electrochemical method of preparation of unsymmetrical disulfides [J].
Do, QT ;
Elothmani, D ;
LeGuillanton, G ;
Simonet, J .
TETRAHEDRON LETTERS, 1997, 38 (19) :3383-3384
[6]   A Convenient Method for the Aerobic Oxidation of Thiols to Disulfides [J].
Dong, Wei-Li ;
Huang, Guang-Ying ;
Li, Zheng-Ming ;
Zhao, Wei-Guang .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (08) :2058-2065
[7]   Efficient synthesis of disulfides by air oxidation of thiols under sonication [J].
Garcia Ruano, Jose Luis ;
Parra, Alejandro ;
Aleman, Jose .
GREEN CHEMISTRY, 2008, 10 (06) :706-711
[8]  
Greene T.W., 2007, PROTECTIVE GROUPS OR
[9]  
Groenewegen P., 1979, TETRAHEDRON LETT, V20, P2817
[10]   Oxidative Coupling of Thiols to Disulfides in Solution with Tripropylammonium Halochromates, (C3H7)3NH[CrO3X], (X = F, Cl) Adsorbed on Alumina [J].
HassaniJoshaghani, Ali ;
Ghammamy, Shahriare ;
Bagi, Shahryar ;
Moghimi, Ali ;
Javanshir, Zahra .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (01) :164-170
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