Simple Route for the Synthesis of Copper Hydroxy Salts

被引：80

作者：

Mauricio Aguirre, Jhon ^{[2
,4
]}

Gutierrez, Adamo ^{[3
,4
]}

Giraldo, Oscar ^{[1
,4
]}

机构：

[1] Univ Nacl Colombia, Dept Quim & Fis, Manizales, Colombia

[2] Univ Nacl Colombia, Dept Ingn Quim, Manizales, Colombia

[3] Univ Nacl Colombia, Dept Ingn Elect Elect Elect & Computac, Manizales, Colombia

[4] Univ Nacl Colombia, Lab Mat Nanoestruct & Func, Manizales, Colombia

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2011年 / 22卷 / 03期

关键词：

hydroxy salts; anionic clay; copper hydroxynitrate; gerhardtite; ANION-EXCHANGE REACTIONS; MAGNETIC-PROPERTIES; LAYERED COMPOUNDS; UREA HYDROLYSIS; ZINC; FERROMAGNETISM; INTERCALATION; SPECTROSCOPY; BEHAVIOR; ACETATE;

D O I：

10.1590/S0103-50532011000300019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The current work introduces a new and rapid synthetic route for the in-laboratory preparation of copper hydroxy nitrate, through the reaction of magnesium hydroxide and copper nitrate aqueous solution. The material with the formula Cu-2(OH)(3)NO3 and monoclinic phase was characterized by X-ray diffraction, atomic absorption, Fourier transform infrared and Raman spectroscopy, scanning electron microscopy with EDX, and thermal analysis.

引用

页码：546 / 551

页数：6

共 31 条

[1] Ab initio crystal structure of copper(II) hydroxy-terephthalate by synchrotron powder diffraction and magnetic properties [J].

Abdelouhab, S ;

François, M ;

Elkaim, E ;

Rabu, P .

SOLID STATE SCIENCES, 2005, 7 (02) :227-232

[2] Thermal behaviour of hydroxides, hydroxysalts and hydrotalcites [J].

Bera, P ;

Rajamathi, M ;

Hegde, MS ;

Kamath, PV .

BULLETIN OF MATERIALS SCIENCE, 2000, 23 (02) :141-145

[3] Synthesis, characterisation and anion exchange properties of copper, magnesium, zinc and nickel hydroxy nitrates [J].

Biswick, T ;

Jones, W ;

Pacula, A ;

Serwicka, E .

JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (01) :49-55

[4]

Bruschini C.S., 1995, Access in Nanoporous Materials, P161

[5] Chemical modification of zinc hydroxide nitrate and Zn-Al-layered double hydroxide with dicarboxylic acids [J].

Carbajal Arizaga, Gregorio Guadalupe ;

Mangrich, Antonio Salvio ;

Ferreira da Costa Gardolinski, Jose Eduardo ;

Wypych, Fernando .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 320 (01) :168-176

[6] Layered hydroxide salts: Synthesis, properties and potential applications [J].

Carbajal Arizaga, Gregorio Guadalupe ;

Satyanarayana, Kestur Gundappa ;

Wypych, Fernando .

SOLID STATE IONICS, 2007, 178 (15-18) :1143-1162

[7] Raman spectroscopy of likasite at 298 and 77 K [J].

Frost, RL ;

Erickson, KL ;

Weier, ML ;

Leverett, P ;

Williams, PA .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 61 (04) :607-612

[8] Infrared emission spectroscopic study of brucite [J].

Frost, RL ;

Kloprogge, JT .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1999, 55 (11) :2195-2205

[9] Magnetic properties of Cu-2(OH)(3)(alkanecarboxylate) compounds: Drastic modification with extension of the alkyl chain [J].

Fujita, W ;

Awaga, K .

INORGANIC CHEMISTRY, 1996, 35 (07) :1915-1917

[10] Reversible structural transformation and drastic magnetic change in a copper hydroxides intercalation compound [J].

Fujita, W ;

Awaga, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4563-4564

← 1 2 3 4 →