Rational design of a coordination cage with a trigonal-bipyramidal shape constructed from 33 building units

被引：53

作者：

Müller, IM ^{[1
]}

Möller, D ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Analyt Chem, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 19期

关键词：

self-assembly; bridging ligands; cage compounds; palladium; solid-state structures;

D O I：

10.1002/anie.200463034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) According to plan: C2- and C 3-symmetric ligands are essential to the rational design of a low-symmetry coordination cage with the outer shape of a trigonal bipyramid (view along the C3 axis shown; green: Pd, red: ligand, blue: 5,5-diethylbarbiturate). The characterization of an intermediate gives insight to the mechanism of formation. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2969 / 2973

页数：5

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