Reaction of 9-trimethylsilylfluorenyllithium with nitriles: Organolithium compounds

被引：1

作者：

Chen, Xia ^{[1
,4
]}

Xue, Xiaoyan ^{[1
]}

Zhang, Liping ^{[1
,2
,3
]}

Sun, Wen-Hua ^{[2
,3
]}

机构：

[1] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China

[3] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[4] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 01期

关键词：

9-trimethylsilylfluorenyllithium; eta(3)-allyl; eta(3)-azaallyl; eta(6)-arene; CRYSTAL-STRUCTURE; COMPLEXES; LITHIUM; LIGANDS; METAL; TRANSFORMATION; ALKYLATION; SOLVENT; ALKYLS; CP;

D O I：

10.1016/j.inoche.2010.11.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 9-trimethylsilylfluorenyllithium (C13H8SiMe3)Li (1) with alpha-hydrogen-free nitriles gave highly sensitive lithium compounds, (eta(3)-C13H8SiMe3)Li((BuCN)-Bu-t)(Et2O) (2).[eta(3)-(C13H8)C(NMe2)N(SiMe3)]Li (Er2O)(2) (3) and [eta(3),eta(6)-(C13H8)C(Ph)N(SiMe3)Li](2) (4), illustrating bonding features of eta(3)-allyl, eta(3)-azaallyl, and eta(6)-arene interactions. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：235 / 237

页数：3

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