Reaction of 9-trimethylsilylfluorenyllithium with nitriles: Organolithium compounds

被引：1
|
作者：
Chen, Xia [1 ,4 ]
Xue, Xiaoyan [1 ]
Zhang, Liping [1 ,2 ,3 ]
Sun, Wen-Hua [2 ,3 ]
机构：
[1] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[4] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 01期
关键词：
9-trimethylsilylfluorenyllithium; eta(3)-allyl; eta(3)-azaallyl; eta(6)-arene; CRYSTAL-STRUCTURE; COMPLEXES; LITHIUM; LIGANDS; METAL; TRANSFORMATION; ALKYLATION; SOLVENT; ALKYLS; CP;
D O I：
10.1016/j.inoche.2010.11.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 9-trimethylsilylfluorenyllithium (C13H8SiMe3)Li (1) with alpha-hydrogen-free nitriles gave highly sensitive lithium compounds, (eta(3)-C13H8SiMe3)Li((BuCN)-Bu-t)(Et2O) (2).[eta(3)-(C13H8)C(NMe2)N(SiMe3)]Li (Er2O)(2) (3) and [eta(3),eta(6)-(C13H8)C(Ph)N(SiMe3)Li](2) (4), illustrating bonding features of eta(3)-allyl, eta(3)-azaallyl, and eta(6)-arene interactions. (C) 2010 Elsevier B.V. All rights reserved.
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页码：235 / 237
页数：3
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