Triplet emission in soluble mercury(II) polyyne polymers

被引：90

作者：

Wong, WY ^{[1
]}

Liu, L ^{[1
]}

Shi, JX ^{[1
]}

机构：

[1] Hong Kong Baptist Univ, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 34期

关键词：

aggregation; alkyne ligands; luminescence; mercury; polymers;

D O I：

10.1002/anie.200351672

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The light fantastic: The first examples of soluble high-molecular-weight d10 mercury(II) polyyne copolymers incorporating a 9,9-dialkylfluorene moiety have been prepared and photophysically characterized (see picture). These polymers have been shown to utilize a heavy-atom effect in exhibiting strong phosphorescence.

引用

页码：4064 / 4068

页数：5