Triplet emission in soluble mercury(II) polyyne polymers

被引：90
作者：
Wong, WY [1 ]
Liu, L [1 ]
Shi, JX [1 ]
机构：
[1] Hong Kong Baptist Univ, Dept Chem, Kowloon, Hong Kong, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 34期
关键词：
aggregation; alkyne ligands; luminescence; mercury; polymers;
D O I：
10.1002/anie.200351672
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The light fantastic: The first examples of soluble high-molecular-weight d10 mercury(II) polyyne copolymers incorporating a 9,9-dialkylfluorene moiety have been prepared and photophysically characterized (see picture). These polymers have been shown to utilize a heavy-atom effect in exhibiting strong phosphorescence.
引用
收藏
页码：4064 / 4068
页数：5
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