Improved dehydrogenation properties of Ca(BH4)2-LiNH2 combined system

被引：32
作者：
Chu, Hailiang [1 ]
Xiong, Zhitao [1 ]
Wu, Guotao [1 ]
Guo, Jianping [1 ]
He, Teng [1 ]
Chen, Ping [1 ]
机构：
[1] Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 44期
基金：
中国国家自然科学基金;
关键词：
HYDROGEN-STORAGE; CALCIUM BOROHYDRIDE; REVERSIBILITY; DESORPTION;
D O I：
10.1039/c0dt00294a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ca(BH4)(2)-LiNH2 combined system is shown to release hydrogen at much lower temperature compared to the pure Ca(BH4)(2). The improved dehydrogenation in this system can be ascribed to a combination reaction between [BH4] and [NH2] based on the reaction mechanism of positive H and negative H.
引用
收藏
页码：10585 / 10587
页数：3
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