A Luminescent 1D Silver Polymer Containing [2.2]Paracyclophane Ligands

被引：8

作者：

Mackenzie, Campbell F. R. ^{[1
]}

Delforce, Lucie ^{[1
]}

Martir, D. Rota ^{[1
]}

Cordes, David B. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Zysman-Colman, Eli ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, Organ Semicond Ctr, St Andrews, Fife, Scotland

来源：

FRONTIERS IN CHEMISTRY | 2021年 / 9卷

基金：

英国工程与自然科学研究理事会;

关键词：

coordination polymer; cyclophane; supramolecular chemistry; silver(I); paracyclophane; COORDINATION POLYMERS; COMPLEXES; DESIGN;

D O I：

10.3389/fchem.2021.728845

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.

引用

页数：6

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