Photoelectrochemical solar cell using extract of Eugenia jambolana Lam as a natural sensitizer

被引:26
作者
Garcia, CG [1 ]
Polo, AS [1 ]
Iha, NYM [1 ]
机构
[1] Univ Sao Paulo, Inst Quim, BR-05508900 Sao Paulo, SP, Brazil
来源
ANAIS DA ACADEMIA BRASILEIRA DE CIENCIAS | 2003年 / 75卷 / 02期
关键词
photoclectrochemical solar cell; natural dye; Jambolao ([!text type='java']java[!/text] plum); energy conversion; dye sensitized solar cells;
D O I
10.1590/S0001-37652003000200004
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The extract of Jambolao (java plum), Eugenia jambolana Lam, was used as a natural sensitizer of a wide band-gap semiconductor (TiO2?) in photoelectrochemical solar cells. The natural dye, adsorbed onto the semiconductor surface. absorbs visible light and promotes electron transfer across the dye/semiconductor interface. Photogenerated current and voltage as high as 2.3 mA and 711 mV, respectively, were obtained and effective conversion of visible light into electricity was achieved. The use of a natural product as the semiconductor sensitizer enables a faster and simpler production of cheaper and environmentally friendly solar cells.
引用
收藏
页码:163 / 165
页数:3
相关论文
共 19 条
[1]  
Bignozzi CA, 1997, PROG INORG CHEM, V44, P1
[2]   Ultrafast electron injection: Implications for a photoelectrochemical cell utilizing an anthocyanin dye-sensitized TiO2 nanocrystalline electrode [J].
Cherepy, NJ ;
Smestad, GP ;
Gratzel, M ;
Zhang, JZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (45) :9342-9351
[3]   Photosensitization of nanocrystalline TiO2 films by anthocyanin dyes [J].
Dai, Q ;
Rabani, J .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) :17-24
[4]   Unusually efficient photosensitization of nanocrystalline TiO2 films by pomegranate pigments in aqueous medium [J].
Dai, Q ;
Rabani, J .
NEW JOURNAL OF CHEMISTRY, 2002, 26 (04) :421-426
[5]   Photosensitization of nanocrystalline TiO2 films by pomegranate pigments with unusually high efficiency in aqueous medium [J].
Dai, Q ;
Rabani, J .
CHEMICAL COMMUNICATIONS, 2001, (20) :2142-2143
[6]  
Garcia C. G., 2001, INT J PHOTOENERGY, V3, P137
[7]  
Garcia C. G., 2001, INT J PHOTOENERGY, V3, P131
[8]   4-Phenylpyridine as ancillary ligand in ruthenium(II) polypyridyl complexes for sensitization of n-type TiO2 electrodes [J].
Garcia, CG ;
Iha, NYM ;
Argazzi, R ;
Bignozzi, CA .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1998, 115 (03) :239-242
[9]   Sensitization of n-type TiO2 electrode by a novel isoquinoline ruthenium(II) polypyridyl complex [J].
Garcia, CG ;
Iha, NYM ;
Argazzi, R ;
Bignozzi, CA .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 1998, 9 (01) :13-15
[10]   Time-resolved experiments in dye-sensitized solar cells using [(dcbH2)2Ru(ppy)2](ClO4)2 as a nanocrystalline TiO2 sensitizer [J].
Garcia, CG ;
Kleverlaan, CJ ;
Bignozzi, CA ;
Iha, NYM .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 147 (02) :143-148