Methyl 7-hydroxy-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropteridine-6-carboxylate-dimethyl sulfoxide (1/1) forms chains containing O-H•••O and C-H•••O hydrogen bonds and aromatic π-π-stacking interactions

被引:3
作者
Cannon, D
Low, JN
Cobo, J
Molina, S
Nogueras, M
Sánchez, A
Glidewell, C [1 ]
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Dundee, Dept Elect Engn & Phys, Dundee DD1 4HN, Scotland
[3] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland
[4] Univ Jaen, Dept Quim Inorgan & Organ, Jaen 23071, Spain
关键词
D O I
10.1107/S0108270101003250
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, C11H12N4O5.C2H6OS, the molecular components are linked by a short hydrogen bond with dimensions O . . . O 2.517 (2) Angstrom and O--H . . . O 168 degrees. Paired C--H . . . O hydrogen bonds [C . . .O 3.362 (2) and 3.382 (2)Angstrom; C--H . . . O 157 and 140 degrees] generate cyclic centrosymmetric four-component aggregates reinforced by aromatic pi-pi -stacking interactions, and further C--H . . . O hydrogen bonds [C . . . O 3.472 (3) and 3.521 (2) Angstrom; C--H . . . O 156 and 157 degrees] link these aggregates into chains.
引用
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页码:608 / 610
页数:3
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