Chemical Vapor Deposition of Photocatalyst Nanoparticles on PVDF Membranes for Advanced Oxidation Processes

被引:40
作者
De Filpo, Giovanni [1 ]
Pantuso, Elvira [2 ]
Armentano, Katia [2 ]
Formoso, Patrizia [2 ]
Di Profio, Gianluca [3 ]
Poerio, Teresa [3 ]
Fontananova, Enrica [3 ]
Meringolo, Carmen [3 ]
Mashin, Alexander I. [4 ]
Nicoletta, Fiore P. [1 ]
机构
[1] Univ Calabria, Dept Chem & Chem Technol, Via P Bucci Cubo 15-C, I-87036 Arcavacata Di Rende, CS, Italy
[2] Univ Calabria, Dept Pharm Hlth & Nutr Sci, Via P Bucci,Edificio Polifunz, I-87036 Arcavacata Di Rende, CS, Italy
[3] Natl Res Council Italy CNR, Inst Membrane Technol ITM, Via P Bucci Cubo 17-C, I-87036 Arcavacata Di Rende, CS, Italy
[4] Lobachevsky State Univ Nizhni Novgorod, Appl Phys & Microelect, Nizhnii Novgorod 603950, Russia
关键词
chemical vapor deposition; polyvinylidene difluoride; titanium dioxide; zinc oxide; photocatalysis; ENVIRONMENTAL APPLICATIONS; PHARMACEUTICAL RESIDUES; AQUATIC ENVIRONMENT; TIO2; NANOPARTICLES; HYBRID HYDROGELS; ORGANIC-MATTER; DEGRADATION; REMOVAL; DISTILLATION; DRUGS;
D O I
10.3390/membranes8030035
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The chemical binding of photocatalytic materials, such as TiO2 and ZnO nanoparticles, onto porous polymer membranes requires a series of chemical reactions and long purification processes, which often result in small amounts of trapped nanoparticles with reduced photocatalytic activity. In this work, a chemical vapor deposition technique was investigated in order to allow the nucleation and growth of ZnO and TiO2 nanoparticles onto polyvinylidene difluoride (PVDF) porous membranes for application in advanced oxidation processes. The thickness of obtained surface coatings by sputtered nanoparticles was found to depend on process conditions. The photocatalytic efficiency of sputtered membranes was tested against both a model drug and a model organic pollutant in a small continuous flow reactor.
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页数:15
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