Anhydrous photochemical reduction of well-defined uranyl(VI) complexes

被引：3

作者：

Duval, Paul B. ^{[1
]}

Kannan, Shanmugaperumal ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2007年 / 444卷

关键词：

actinide alloys and compounds; chemical synthesis; X-ray diffraction;

D O I：

10.1016/j.jallcom.2006.11.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photochemical reactivity of well-defined cationic uranyl(VI) complexes is presented under non-aqueous conditions employing systematic control over variable experimental conditions, with a focus on structural and electronic characterization of the products. The results offer mechanistic insight into alternate pathways of dioxo activation during the photochemical reduction of uranyl(VI) that are operable only under anhydrous conditions. (c) 2006 Elsevier B.V. All rights reserved.

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收藏

页码：673 / 676

页数：4

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