Ultrafast Photophysics of 2D Semiconductors and Related Heterostructures

被引：50

作者：

Dal Conte, Stefano ^{[1
]}

Trovatello, Chiara ^{[1
]}

Gadermaier, Christoph ^{[1
,2
]}

Cerullo, Giulio ^{[1
,3
]}

机构：

[1] Politecn Milan, Dept Phys, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy

[2] Italian Inst Technol, Ctr Nano Sci & Technol, Via Pascoli 70-3, I-20133 Milan, Italy

[3] IFN CNR, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy

来源：

TRENDS IN CHEMISTRY | 2020年 / 2卷 / 01期

基金：

欧盟地平线“2020”;

关键词：

PHOTOINDUCED BANDGAP RENORMALIZATION; CARRIER DYNAMICS; CHARGE-TRANSFER; 2-DIMENSIONAL MATERIALS; VALLEY POLARIZATION; EXCITON FORMATION; MONOLAYER MOS2; SPIN; GRAPHENE; OPTOELECTRONICS;

D O I：

10.1016/j.trechm.2019.07.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Atomically thin transition-metal dichalcogenides (TMDs) exhibit strong light-matter interaction and pronounced excitonic behavior. Understanding the nonequilibrium dynamical processes of photoexcited carriers in such materials is a key step in view of their technological applications. Here, we review the ultrafast photophysics of 2D TMDs and related heterostructures (HSs) measured by femtosecond optical spectroscopy. First, we provide a general introduction on the physics of the materials and a brief explanation of the ultrafast optical techniques. Then we discuss the physical processes governing their nonequilibriumoptical response, with a particular emphasis on the intervalley scattering dynamics, and the charge-transfer processes in 2D HSs. We conclude by discussing open issues and perspectives for future experiments.

引用

页码：28 / 42

页数：15

共 111 条

[1] Many-body effects in nonlinear optical responses of 2D layered semiconductors [J].

Aivazian, Grant ;

Yu, Hongyi ;

Wu, Sanfeng ;

Yan, Jiaqiang ;

Mandrus, David G. ;

Cobden, David ;

Yao, Wang ;

Xu, Xiaodong .

2D MATERIALS, 2017, 4 (02)

[2] Resonantly hybridized excitons in moire superlattices in van der Waals heterostructures [J].

Alexeev, Evgeny M. ;

Ruiz-Tijerina, David A. ;

Danovich, Mark ;

Hamer, Matthew J. ;

Terry, Daniel J. ;

Nayak, Pramoda K. ;

Ahn, Seongjoon ;

Pak, Sangyeon ;

Lee, Juwon ;

Sohn, Jung Inn ;

Molas, Maciej R. ;

Koperski, Maciej ;

Watanabe, Kenji ;

Taniguchi, Takashi ;

Novoselov, Kostya S. ;

Gorbachev, Roman V. ;

Shin, Hyeon Suk ;

Fal'ko, Vladimir I. ;

Tartakovskii, Alexander I. .

NATURE, 2019, 567 (7746) :81-+

[3] Near-unity photoluminescence quantum yield in MoS2 [J].

Amani, Matin ;

Lien, Der-Hsien ;

Kiriya, Daisuke ;

Xiao, Jun ;

Azcatl, Angelica ;

Noh, Jiyoung ;

Madhvapathy, Surabhi R. ;

Addou, Rafik ;

Santosh, K. C. ;

Dubey, Madan ;

Cho, Kyeongjae ;

Wallace, Robert M. ;

Lee, Si-Chen ;

He, Jr-Hau ;

Ager, Joel W., III ;

Zhang, Xiang ;

Yablonovitch, Eli ;

Javey, Ali .

SCIENCE, 2015, 350 (6264) :1065-1068

[4] Inverted valley polarization in optically excited transition metal dichalcogenides [J].

Berghauser, Gunnar ;

Bernal-Villamil, Ivan ;

Schmidt, Robert ;

Schneider, Robert ;

Niehues, Iris ;

Erhart, Paul ;

de Vasconcellos, Steffen Michaelis ;

Bratschitsch, Rudolf ;

Knorr, Andreas ;

Malic, Ermin .

NATURE COMMUNICATIONS, 2018, 9

[5] Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage [J].

Bonaccorso, Francesco ;

Colombo, Luigi ;

Yu, Guihua ;

Stoller, Meryl ;

Tozzini, Valentina ;

Ferrari, Andrea C. ;

Ruoff, Rodney S. ;

Pellegrini, Vittorio .

SCIENCE, 2015, 347 (6217)

[6] Charge Photogeneration in Few-Layer MoS2 [J].

Borzda, Tetiana ;

Gadermaier, Christoph ;

Vujicic, Natasa ;

Topolovsek, Peter ;

Borovsak, Milos ;

Mertelj, Tomaz ;

Viola, Daniele ;

Manzoni, Cristian ;

Pogna, Eva A. A. ;

Brida, Daniele ;

Antognazza, Maria Rosa ;

Scotognella, Francesco ;

Lanzani, Guglielmo ;

Cerullo, Giulio ;

Mihailovic, Dragan .

ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (22) :3351-3358

[7] Exciton Relaxation Cascade in two-dimensional Transition Metal Dichalcogenides [J].

Brem, Samuel ;

Selig, Malte ;

Berghaeuser, Gunnar ;

Malic, Ermin .

SCIENTIFIC REPORTS, 2018, 8

[8] Observation of Ultrafast Free Carrier Dynamics in Single Layer MoS2 [J].

Cabo, Antonija Grubisic ;

Miwa, Jill A. ;

Gronborg, Signe S. ;

Riley, Jonathon M. ;

Johannsen, Jens C. ;

Cacho, Cephise ;

Alexander, Oliver ;

Chapman, Richard T. ;

Springate, Emma ;

Grioni, Marco ;

Lauritsen, Jeppe V. ;

King, Phil D. C. ;

Hofmann, Philip ;

Ulstrup, Soren .

NANO LETTERS, 2015, 15 (09) :5883-5887

[9] Valley-selective circular dichroism of monolayer molybdenum disulphide [J].

Cao, Ting ;

Wang, Gang ;

Han, Wenpeng ;

Ye, Huiqi ;

Zhu, Chuanrui ;

Shi, Junren ;

Niu, Qian ;

Tan, Pingheng ;

Wang, Enge ;

Liu, Baoli ;

Feng, Ji .

NATURE COMMUNICATIONS, 2012, 3

[10] Ultrafast Laser Spectroscopy of Two-Dimensional Materials Beyond Graphene [J].

Ceballos, Frank ;

Zhao, Hui .

ADVANCED FUNCTIONAL MATERIALS, 2017, 27 (19)

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