Bipolar membrane electrodialysis in aqua-ethanol medium: Production of salicylic acid

被引:57
作者
Liu, Xiaohe [1 ]
Li, Qiuhua [1 ]
Jiang, Chenxiao [1 ]
Lin, Xiaocheng [1 ]
Xu, Tongwen [1 ]
机构
[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Collaborat Innovat Ctr Chem Energy Mat, Sch Chem & Mat Sci, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Bipolar membrane; Electrodialysis; Aqua-ethanol medium; Salicylic acid; CITRIC-ACID;
D O I
10.1016/j.memsci.2015.02.030
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
To overcome the low solubility of salicylic acid (SAH) in the production process by bipolar membrane electrodialysis (BMED), the water-ethanol mixture as solution medium was introduced in the BMED technique. The results indicated that the highest acid concentration was obtained when ethanol content was 50 v/v%, and the current efficiency reached 982%. Moreover, the BMED stack of BP-C (BP, bipolar membrane; C, cation exchange membrane) configuration was proved as most cost-effective configuration, and using this configuration the highest current efficiency could reach 99.6% and the lowest energy consumption was 2.1 kW h kg(-1). (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:76 / 82
页数:7
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