Unsymmetrical beta-diketones, monothio-beta-diketones and their nickel(II) and cobalt(III) complexes

被引：3

作者：

Das, M ^{[1
]}

Haworth, DT ^{[1
]}

机构：

[1] MARQUETTE UNIV,DEPT CHEM,MILWAUKEE,WI 53201

来源：

TRANSITION METAL CHEMISTRY | 1996年 / 21卷 / 05期

关键词：

D O I：

10.1007/BF00140788

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unsymmetrically substituted beta-diketones, RCOCH(2)COR' (R and R' = aryl) have been synthesized and used to prepare their monothio-beta-diketone derivatives. Because of the similar basicities of the carbonyl oxygen due to the electronic effects of the R and R' groups, a mixture of the monothio-beta-diketones, RCSCH(2)COR' and R'CSCH(2)COR, is formed. Several of the monothio-beta-diketones have been used to prepare their corresponding Ni-II and Co-II complexes. Mass spectral and C-13-n.m.r. data are used to confirm the formation of isomers of the monothio-beta-diketonate ligands and their metal complexes.

引用

页码：442 / 446

页数：5

共 14 条

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