Catalytic ethenylation reaction of phenol using SnCl4

被引:17
作者
Kobayashi, K [1 ]
Yamaguchi, M [1 ]
机构
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Sendai, Miyagi 9808578, Japan
关键词
D O I
10.1021/ol006888d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Ethenylation reaction of phenol with silylethyne at the o-position is catalyzed by the SnCl4-BuLi reagent. While turn over numbers (TONs) in the reactions of m- or p-substituted phenols are 3 to 4, those for o-substituted phenols are 8 to 9.
引用
收藏
页码:241 / 242
页数:2
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