Synthesis of chiral mesostructured titanium dioxide films

被引:11
作者
Zhang, Fenping [1 ]
Ai, Jing [2 ]
Ding, Kun [1 ]
Duan, Yingying [2 ]
Han, Lu [2 ]
Che, Shunai [1 ,2 ]
机构
[1] Shanghai Jiaa Tong Univ, Shanghai Key Lab Mol Engn Chiral Drugs, State Key Lab Composite Mat, Sch Chem & Chem Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
[2] Tongji Univ, Sch Chem Sci & Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China
基金
中国国家自然科学基金;
关键词
MESOPOROUS SILICA; GOLD;
D O I
10.1039/d0cc00669f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral mesostructured TiO(2)films (CMTFs) were synthesized by a hydrothermal method usingl/d-mannitol as the symmetry-breaking agent and titanium foil as both the substrate and inorganic precursor. Five levels of hierarchical chirality exist in the CMTFs, exhibiting optical activity (OA) at similar to 350 nm attributed to the electronic transitions in a dissymmetric electric field.
引用
收藏
页码:4848 / 4851
页数:4
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