On the theory of the stability of dipole molecule solution interlayers in apolar solvents: 1. Thermodynamics of solution film

被引:6
|
作者
Boinovich, LB [1 ]
Emelyanenko, AM [1 ]
机构
[1] Russian Acad Sci, Inst Phys Chem, Moscow 119991, Russia
关键词
D O I
10.1023/B:COLL.0000009108.30457.cc
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermodynamics of the film of solution with apolar solvent and polar solute is analyzed. The expression for calculating disjoining pressure in a film via the potential electric energy of the filed generated by the solute dipoles is derived. The effect of the image forces on the orientation of dipole molecules near the interfaces is considered.
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页码:672 / 677
页数:6
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