Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3with 1,2-dichloroethane

被引：0

作者：

Tugashov, K. I. ^{[1
]}

Yunusov, S. M. ^{[1
]}

Kalyuzhnaya, E. S. ^{[1
]}

Dolgushin, F. M. ^{[1
]}

Tikhonova, I. A. ^{[1
]}

Shur, V. B. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, 28 Ul Vavilova, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2020年 / 69卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

anticrowns; macrocyclic multidentate Lewis acids; polymercuramacrocycles; dihaloalkanes; complexes; mercury; X-ray diffraction analysis; 1; 2-dichloroethane; organomercury compounds; ORTHO-PHENYLENEMERCURY; NONCOVALENT INTERACTIONS; O-PHENYLENEMERCURY; (O-C6F4HG)(3); ACETONITRILE; DISCRETE; ADDUCTS; XYLENE;

D O I：

10.1007/s11172-020-2872-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of perfluorinated three-mercury anticrown (o-C6F4Hg)(3)(1) with 1,2-dichloroethane (DCE) affords the complex {[(o-C6F4Hg)(3)](2)(ClCH2CH2Cl)}(2) containing two anticrown molecules per DCE molecule. According to the X-ray diffraction data, the DCE molecule in complex2acts as a bridge between molecules1, each DCE chlorine atom being coordinated to a single mercury center of the neighboring anticrown molecules.

引用

页码：1092 / 1095

页数：4

共 18 条

[1] Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3 with 1,2-dichloroethane
K. I. Tugashov
S. M. Yunusov
E. S. Kalyuzhnaya
F. M. Dolgushin
I. A. Tikhonova
V. B. Shur
Russian Chemical Bulletin, 2020, 69 : 1092 - 1095
[2] Coordination chemistry of anticrowns. An unusual complex of perfluorinated three-mercury anticrown (o-C6F4Hg)3withp-bromotoluene and 1,2-dichloroethane
Tugashov, K. I.
Yunusov, S. M.
Kalyuzhnaya, E. S.
Dolgushin, F. M.
Tikhonova, I. A.
Shur, V. B.
RUSSIAN CHEMICAL BULLETIN, 2020, 69 (06) : 1195 - 1198
[3] Coordination chemistry of anticrowns. An unusual complex of perfluorinated three-mercury anticrown (o-C6F4Hg)3 with p-bromotoluene and 1,2-dichloroethane
K. I. Tugashov
S. M. Yunusov
E. S. Kalyuzhnaya
F. M. Dolgushin
I. A. Tikhonova
V. B. Shur
Russian Chemical Bulletin, 2020, 69 : 1195 - 1198
[4] Coordination Chemistry of Anticrowns. Interaction of the Perfluorinated Three-Mercury Anticrown (o-C6F4Hg)3 with Azacrowns
Tugashov, Kirill I.
Gribanyov, Dmitry A.
Dolgushin, Fedor M.
Smol'yakov, Alexander F.
Peregudov, Alexander S.
Klemenkova, Zinaida S.
Barakovskaya, Irina G.
Tikhonova, Irina A.
Shur, Vladimir B.
ORGANOMETALLICS, 2019, 38 (15) : 2910 - 2918
[5] Coordination Chemistry of Anticrowns. Synthesis and Structures of Complexes of the Perfluorinated Three-Mercury Anticrown (o-C6F4Hg)3 with Monohalogenobenzenes
Tugashov, Kirill I.
Yunusov, Safar M.
Kalyuzhnaya, Elena S.
Dolgushin, Fedor M.
Peregudov, Alexander S.
Klemenkova, Zinaida S.
Minacheva, Marija Kh.
Tikhonova, Irina A.
Shur, Vladimir B.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (47) : 5018 - 5024
[6] Coordination chemistry of mercury-containing anticrowns. Complexation of nitrate and sulfate anions with the three-mercury anticrown (o-C6F4Hg)3 and the influence of the nature of a countercation on the structure of the resulting nitrate complexes
Tugashov, K. I.
Gribanyov, D. A.
Dolgushin, F. M.
Smol'yakov, A. F.
Peregudov, A. S.
Minacheva, M. Kh.
Strunin, B. N.
Tikhonova, I. A.
Shur, V. B.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 747 : 167 - 173
[7] Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules
Tugashov, Kirill I.
Gribanyov, Dmitry A.
Dolgushin, Fedor M.
Smol'yakov, Alexander F.
Peregudov, Alexander S.
Minacheva, Marija Kh.
Tikhonova, Irina A.
Shur, Vladimir B.
ORGANOMETALLICS, 2016, 35 (13) : 2197 - 2206
[8] Coordination chemistry of mercury-containing anticrowns. Self-assembly of unusual supramolecular aggregates in the interaction of the three-mercury anticrown (o-C6F4Hg)3 with crown ethers in the presence of neutral monodentate oxygenous Lewis bases
Tikhonova, Irina A.
Gribanyov, Dmitry A.
Tugashov, Kirill I.
Dolgushin, Fedor M.
Smol'yakov, Alexandr F.
Peregudov, Alexandr S.
Klemenkova, Zinaida S.
Shur, Vladimir B.
ARKIVOC, 2011, : 172 - 184
[9] Coordination chemistry of anticrowns. Synthesis and structure of a complex of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 with tungsten hexacarbonyl
Tugashov, K. I.
Yunusov, S. M.
Kalyuzhnaya, E. S.
Dolgushin, F. M.
Yakovenko, A. A.
Tikhonova, I. A.
Shur, V. B.
RUSSIAN CHEMICAL BULLETIN, 2018, 67 (01) : 45 - 49
[10] Coordination chemistry of anticrowns. Synthesis and structure of a complex of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 with tungsten hexacarbonyl
K. I. Tugashov
S. M. Yunusov
E. S. Kalyuzhnaya
F. M. Dolgushin
A. A. Yakovenko
I. A. Tikhonova
V. B. Shur
Russian Chemical Bulletin, 2018, 67 : 45 - 49

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