Star poly(ethylene oxide)s from carbosilane dendrimers

被引：92

作者：

Comanita, B ^{[1
]}

Noren, B ^{[1
]}

Roovers, J ^{[1
]}

机构：

[1] Natl Res Council Canada, Inst Chem Proc & Environm Technol, Ottawa, ON K1A 0R6, Canada

来源：

MACROMOLECULES | 1999年 / 32卷 / 04期

关键词：

D O I：

10.1021/ma981201e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of 4-arm, 8-arm, and 16-arm poly(ethylene oxide)s (PEO) have been synthesized from hydroxy functionalized carbosilane dendrimers of generation zero, one, and two, respectively. The PEO arms are grown anionically from the multifunctional cores. The polymers have narrow molecular weight distributions. Analysis of the molecular weight, intrinsic viscosity, and translational diffusion coefficient in methanol confirms the star structure of the polymers. The aqueous solutions of the star PEOs appear normal. Low molecular weight star polymers, however, show abnormally low intrinsic viscosities and are adsorbed on the size exclusion column hydrogel material.

引用

页码：1069 / 1072

页数：4

共 50 条

[31] Osmotic second virial coefficient for linear and star poly(ethylene oxide)
Striolo, A
Prausnitz, JM
POLYMER, 2001, 42 (10) : 4773 - 4775
[32] Star poly(ethylene oxide) as a low temperature electrolyte and crystallization inhibitor
Stowe, MK
Liu, P
Baker, GL
CHEMISTRY OF MATERIALS, 2005, 17 (26) : 6555 - 6559
[33] Association and phase separation of amphiphilic poly(ethylene oxide) star polymers
Zhou, GB
Chen, X
Smid, J
HYDROPHILIC POLYMERS: PERFORMANCE WITH ENVIRONMENTAL ACCEPTANCE, 1996, 248 : 31 - 47
[34] Crystallization kinetics of poly(ethylene oxide) in poly(ethylene oxide) polystyrene poly(ethylene oxide) triblock copolymers
Floudas, G
Tsitsilianis, C
MACROMOLECULES, 1997, 30 (15) : 4381 - 4390
[35] FROM STAR-SHAPED TO DENDRITIC POLY(ETHYLENE OXIDE)S - TOWARD INCREASINGLY BRANCHED ARCHITECTURES BY ANIONIC-POLYMERIZATION
SIX, JL
GNANOU, Y
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 189 - POLY
[36] FROM STAR-SHAPED TO DENDRITIC POLY(ETHYLENE OXIDE)S - TOWARD INCREASINGLY BRANCHED ARCHITECTURES BY ANIONIC-POLYMERIZATION
SIX, JL
GNANOU, Y
MACROMOLECULAR SYMPOSIA, 1995, 95 : 137 - 150
[37] Enhanced interfacial activity of multi-arm poly(ethylene oxide) star polymers relative to linear poly(ethylene oxide) at fluid interfaces
Huang, Yun-Ru
Lamson, Melissa
Matyjaszewski, Krzysztof
Tilton, Robert D.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (35) : 23854 - 23868
[38] RAMAN-SCATTERING FROM MIXTURES OF POLY(ETHYLENE OXIDE) 2000 WITH POLY(ETHYLENE OXIDE) 200
HARTLEY, AJ
LEUNG, YK
MCMAHON, J
BOOTH, C
SHEPHERD, IW
POLYMER, 1977, 18 (04) : 336 - 340
[39] Effects of Poly(Propylene Oxide)-Poly(Ethylene Oxide)-Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Aqueous Solutions
Xie, Yu
Tang, Jiankai
Lu, Zhongyuan
Sun, Zhaoyan
An, Lijia
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2013, 52 (09): : 1183 - 1197
[40] Adsorption mechanism(s) of poly(ethylene oxide) on oxide surfaces
Mathur, S
Moudgil, BM
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 196 (01) : 92 - 98

← 1 2 3 4 5 →