Bis(2-methylpyridinium) tetrachloridocuprate(II): synthesis, structure and Hirshfeld surface analysis

被引：3
|
作者：
Mehmood, Tahir [1 ]
Bhosale, Rajesh S. [1 ]
Reddy, J. Prakasha [1 ]
机构：
[1] Indrashil Univ, Sch Sci, Dept Chem, Rajpur 382740, Gujarat, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
2-picoline complex; inorganic supramolecular chemistry; crystal structure; hydrogen bonding; CRYSTAL-STRUCTURE; POLYMORPHISM;
D O I：
10.1107/S2056989021006277
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C6H8N)(2)[CuCl4], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetrahedron. The 2-methylpyridinium ion (C6H8N+) interacts with the tetrachlorocuprate anion through N-H center dot center dot center dot Cl and C-H(phenyl)center dot center dot center dot Cl contacts, forming a hydrogen-bonded layer-like structure. The supramolecular structure is further stabilized by C-H(methyl)center dot center dot center dot Cl interactions between the layers.
引用
收藏
页码：726 / +
页数：7
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