Synthesis, crystal structure, thermal properties of copper(II) acrylate complex with 4 '-phenyl-2,2 ':6 ',2 ''-terpyridine and its use in nanomaterials science

被引：9

作者：

Uflyand, Igor E. ^{[1
]}

Tkachev, Valerii V. ^{[2
]}

Zhinzhilo, Vladimir A. ^{[1
]}

Drogan, Ekaterina G. ^{[3
]}

Burlakova, Victoria E. ^{[3
]}

Sokolov, Mikhail E. ^{[4
]}

Panyushkin, Victor T. ^{[5
]}

Baimuratova, Rosa K. ^{[2
]}

Dzhardimalieva, Gulzhian, I ^{[2
,6
]}

机构：

[1] Southern Fed Univ, Dept Chem, B Sadovaya Str 105-42, Rostov Na Donu 344006, Russia

[2] RAS, Inst Problems Chem Phys, Academician Semenov Ave 1, Chernogolovka 142432, Moscow Region, Russia

[3] Don State Tech Univ, Dept Chem, Gagarin Sq 1, Rostov Na Donu 344000, Russia

[4] Kuban State Univ, Dept Phys & Tech, Stavropolskaya Str 149, Krasnodar 350040, Russia

[5] Kuban State Univ, Dept Chem & High Technol, Stavropolskaya Str 149, Krasnodar 350040, Russia

[6] Natl Res Univ, Moscow Aviat Inst, Volokolamskoe Shosse 4, Moscow 125993, Russia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1250卷

关键词：

Metal-containing monomer; Metal acrylate; Thermolysis; Nanomaterial; Lubricant additive; METAL-CONTAINING MONOMERS; COORDINATION CHEMISTRY; CATALYTIC APPLICATION; CHELATE MONOMERS; TERPYRIDINE; POLYMERS; LIGANDS; REACTIVITY; ZINC(II); NI(II);

D O I：

10.1016/j.molstruc.2021.131909

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction between copper(II) acrylate and 4 '-phenyl-2,2 ' :6 ' ,2 ''-terpyridine resulted in a new metal containing monomer 1 , which was characterized by elemental analysis, FTIR spectroscopy, and single crystal X-ray diffraction analysis. Complex 1 crystallizes in triclinic form with space group P-1. The chelate node of complex 1 is close to an ideal tetragonal pyramidal structure and includes three nitrogen atoms of the terpyridine ligand and two oxygen atoms of acrylate fragments. Medium-strong hydrogen bond interactions lead to infinite 1D chains. The kinetic and thermodynamic parameters of the thermolysis process of complex 1 were studied. As a result of thermolysis process, nanomaterials of the Cu@C core shell type were obtained. The resulting nanomaterials are effective antiwear and antifriction additives for lubricating oils. (c) 2021 Elsevier B.V. All rights reserved.

引用

页数：8

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