Synthesis, crystal structure, thermal properties of copper(II) acrylate complex with 4 '-phenyl-2,2 ':6 ',2 ''-terpyridine and its use in nanomaterials science

被引：9
作者：
Uflyand, Igor E. [1 ]
Tkachev, Valerii V. [2 ]
Zhinzhilo, Vladimir A. [1 ]
Drogan, Ekaterina G. [3 ]
Burlakova, Victoria E. [3 ]
Sokolov, Mikhail E. [4 ]
Panyushkin, Victor T. [5 ]
Baimuratova, Rosa K. [2 ]
Dzhardimalieva, Gulzhian, I [2 ,6 ]
机构：
[1] Southern Fed Univ, Dept Chem, B Sadovaya Str 105-42, Rostov Na Donu 344006, Russia
[2] RAS, Inst Problems Chem Phys, Academician Semenov Ave 1, Chernogolovka 142432, Moscow Region, Russia
[3] Don State Tech Univ, Dept Chem, Gagarin Sq 1, Rostov Na Donu 344000, Russia
[4] Kuban State Univ, Dept Phys & Tech, Stavropolskaya Str 149, Krasnodar 350040, Russia
[5] Kuban State Univ, Dept Chem & High Technol, Stavropolskaya Str 149, Krasnodar 350040, Russia
[6] Natl Res Univ, Moscow Aviat Inst, Volokolamskoe Shosse 4, Moscow 125993, Russia
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1250卷
关键词：
Metal-containing monomer; Metal acrylate; Thermolysis; Nanomaterial; Lubricant additive; METAL-CONTAINING MONOMERS; COORDINATION CHEMISTRY; CATALYTIC APPLICATION; CHELATE MONOMERS; TERPYRIDINE; POLYMERS; LIGANDS; REACTIVITY; ZINC(II); NI(II);
D O I：
10.1016/j.molstruc.2021.131909
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction between copper(II) acrylate and 4 '-phenyl-2,2 ' :6 ' ,2 ''-terpyridine resulted in a new metal containing monomer 1 , which was characterized by elemental analysis, FTIR spectroscopy, and single crystal X-ray diffraction analysis. Complex 1 crystallizes in triclinic form with space group P-1. The chelate node of complex 1 is close to an ideal tetragonal pyramidal structure and includes three nitrogen atoms of the terpyridine ligand and two oxygen atoms of acrylate fragments. Medium-strong hydrogen bond interactions lead to infinite 1D chains. The kinetic and thermodynamic parameters of the thermolysis process of complex 1 were studied. As a result of thermolysis process, nanomaterials of the Cu@C core shell type were obtained. The resulting nanomaterials are effective antiwear and antifriction additives for lubricating oils. (c) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数：8
相关论文
共 44 条
  • [1] Synthesis, characterization and electrochemistry of 4′-functionalized 2,2′: 6′, 2"-terpyridine ruthenium(II) complexes and their biological activity
    Anthonysamy, Arockiam
    Balasubramanian, Sengottuvelan
    Shanmugaiah, Vellasamy
    Mathivanan, Narayanasamy
    [J]. DALTON TRANSACTIONS, 2008, (16) : 2136 - 2143
  • [2] Thermal behavior of some new complexes bearing ligands with polymerisable groups
    Badea, M.
    Olar, R.
    Marinescu, D.
    Vasile, G.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2006, 85 (02) : 285 - 288
  • [3] Some new acrylate complexes as a criterion in their selection for further co-polymerization reaction
    Badea, M
    Olar, R
    Marinescu, D
    Vasile, G
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 80 (03) : 683 - 685
  • [4] Thermal behaviour of new biological active cadmium mixed ligands complexes
    Badea, Mihaela
    Olar, Rodica
    Marinescu, Dana
    Lazar, Veronica
    Chifiriuc, Carmen
    Vasile, Gina
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 97 (02) : 781 - 785
  • [5] Baimuratova R.K., 2020, KEY ENG MAT, V869, P119, DOI [10.4028/www.scientific.net/KEM.869.119, DOI 10.4028/WWW.SCIENTIFIC.NET/KEM.869.119]
  • [6] Novel Self-Healing Metallocopolymers with Pendent 4-Phenyl-2,2′:6′,2"-terpyridine Ligand: Kinetic Studies and Mechanical Properties
    Baimuratova, Rose K.
    Dzhardimalieva, Gulzhian I.
    Vaganov, Evgeniy V.
    Lesnichaya, Valentina A.
    Kugabaeva, Gulsara D.
    Kydralieva, Kamila A.
    Zhinzhilo, Vladimir A.
    Uflyand, Igor E.
    [J]. POLYMERS, 2021, 13 (11)
  • [7] Effect of the Composition of the Lubricating Medium on the Structure of Surface Layers Formed by the Friction of a Servovite Film
    Burlakova, V. E.
    Drogan, E. G.
    Novikova, A. A.
    Belikova, M. A.
    [J]. JOURNAL OF SURFACE INVESTIGATION, 2019, 13 (02): : 351 - 358
  • [8] Structural features of uranyl acrylate complexes with s-, p-, and d-monovalent metals
    Chekhomova, Olga A.
    Klepov, Vladislav V.
    Pushkin, Denis, V
    Alekseev, Evgeny, V
    Vologzhanina, Anna V.
    Serezhkina, Larisa B.
    Serezhkin, Viktor N.
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2019, 234 (04): : 247 - 256
  • [9] THE COORDINATION CHEMISTRY OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE - THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE AND BIS(4'-PHENYL-2,2'-6',2''-TERPYRIDINE)NICKEL(II) CHLORIDE DECAHYDRATE
    CONSTABLE, EC
    LEWIS, J
    LIPTROT, MC
    RAITHBY, PR
    [J]. INORGANICA CHIMICA ACTA, 1990, 178 (01) : 47 - 54
  • [10] 2,2′: 6′,2"-terpyridines:: From chemical obscurity to common supramolecular motifs
    Constable, Edwin C.
    [J]. CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) : 246 - 253
12345