Biochemical synthesis of water soluble polyanilines: Poly(p-aminobenzoic acid)

被引：37

作者：

Alva, KS ^{[1
]}

Marx, KA ^{[1
]}

Kumar, J ^{[1
]}

Tripathy, SK ^{[1
]}

机构：

[1] UNIV LOWELL,DEPT PHYS,CTR INTELLIGENT BIOMAT,LOWELL,MA 01854

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 12期

关键词：

D O I：

10.1002/marc.1996.030171203

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This report describes the synthesis of a water soluble polyaniline through a biochemical synthetic route. The oxidative free radical coupling mechanism for the synthesis of poly(p-aminobenzoic acid) is catalyzed by horseradish peroxidase in the presence of hydrogen peroxide. The resulting polymer is electrochemically active and undergoes reversible redox reactions. The polymer as synthesized is self doped and undergoes undoping in alkaline or ammonia solutions.

引用

页码：859 / 863

页数：5

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