Organometallic synthesis of nanoparticles

被引:17
作者
Amiens, C. [1 ]
Chaudret, B. [1 ]
机构
[1] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse 04, France
来源
MODERN PHYSICS LETTERS B | 2007年 / 21卷 / 18期
关键词
nanoparticles; organometallic synthesis; metal-organic precursors;
D O I
10.1142/S0217984907013833
中图分类号
O59 [应用物理学];
学科分类号
摘要
Nanoparticles can be synthesized from metal-organic or organometallic precursors, either by classical thermal decomposition, ultrasound activation, photolysis as well as hydrogenation or hydrolysis reactions. The size, size distribution and more importantly surface state of these nanoparticles are much better controlled than when they are produced by chemical or electrochemical reduction of metal salts. Hence, metal or oxide nanoparticles can be obtained that are suitable for fundamental physics at the nanoscale, especially for magnetic studies. This is currently of particular interest as many applications require systems of still smaller sizes, the properties of which are not yet fully understood.
引用
收藏
页码:1133 / 1141
页数:9
相关论文
共 24 条
[1]   MAGNETISM FROM THE ATOM TO THE BULK IN IRON, COBALT, AND NICKEL CLUSTERS [J].
BILLAS, IML ;
CHATELAIN, A ;
DEHEER, WA .
SCIENCE, 1994, 265 (5179) :1682-1684
[2]   PREPARATION OF POLYHYDRIDE COMPLEXES OF RUTHENIUM BY DIRECT HYDROGENATION OF ZEROVALENT OLEFINIC DERIVATIVES - MONONUCLEAR COMPLEXES OF THE TYPE RUH6L2 AND RUH4L3 - SPONTANEOUS H-D EXCHANGE BETWEEN THE PHOSPHINE PROTONS AND THE SOLVENT CATALYZED BY RUH4L3 [J].
CHAUDRET, B ;
POILBLANC, R .
ORGANOMETALLICS, 1985, 4 (10) :1722-1726
[3]  
Collman J.P., 1987, PRINCIPLES APPL ORGA
[4]   Chemisorption on nickel nanoparticles of various shapes: Influence on magnetism [J].
Cordente, N ;
Amiens, C ;
Chaudret, B ;
Respaud, M ;
Senocq, F ;
Casanove, MJ .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (10) :6358-6365
[5]   Platinum nanoparticles stabilized by CO and octanethiol ligands or polymers: FT-IR, NMR, HREM and WAXS studies [J].
Dassenoy, F ;
Philippot, K ;
Ould-Ely, T ;
Amiens, C ;
Lecante, P ;
Snoeck, E ;
Mosset, A ;
Casanove, MJ ;
Chaudret, B .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (07) :703-711
[6]   Superlattices of iron nanocubes synthesized from Fe[N(SiMe3)2]2 [J].
Dumestre, F ;
Chaudret, B ;
Amiens, C ;
Renaud, P ;
Fejes, P .
SCIENCE, 2004, 303 (5659) :821-823
[7]   Structural study of bimetallic CoxRh1-x nanoparticles:: Size and composition effects -: art. no. 235416 [J].
Fromen, MC ;
Lecante, P ;
Casanove, MJ ;
Guillemaud, PB ;
Zitoun, D ;
Amiens, C ;
Chaudret, B ;
Respaud, M ;
Benfield, RE .
PHYSICAL REVIEW B, 2004, 69 (23) :235416-1
[8]  
Greenwood N.N., 1984, CHEM ELEMENTS
[9]   POLYMERS FOR STABILIZATION OF COLLOIDAL COBALT PARTICLES [J].
HESS, PH ;
PARKER, PH .
JOURNAL OF APPLIED POLYMER SCIENCE, 1966, 10 (12) :1915-&
[10]   PREPARATION AND PROPERTIES OF NICKEL FERROFLUIDS [J].
HOON, SR ;
KILNER, M ;
RUSSELL, GJ ;
TANNER, BK .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1983, 39 (1-2) :107-110