Selective Hydrogenolysis of Glycerol Over Cu-ZrO2-MgO Catalysts

被引：19

作者：

Rekha, V. ^{[1
]}

Raju, N. ^{[1
]}

Sumana, C. ^{[2
]}

Douglas, S. Paul ^{[3
]}

Lingaiah, N. ^{[1
]}

机构：

[1] CSIR Indian Inst Chem Technol, I&PC Div, Catalysis Lab, Hyderabad 500007, Telangana, India

[2] CSIR Indian Inst Chem Technol, Div Chem Engn, Hyderabad 500007, Telangana, India

[3] Andhra Univ, Coll Engn A, Visakhapatnam 530003, Andhra Pradesh, India

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 08期

关键词：

Glycerol hydrogenolysis; Propylene glycol; Copper; Zirconia; Magnesia; BIODIESEL DERIVED GLYCEROL; PROPYLENE-GLYCOL; 1,2-PROPANEDIOL; RU; PROPANEDIOL; NICKEL;

D O I：

10.1007/s10562-016-1775-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cu-ZrO2-MgO catalysts with varying Cu and ZrO2 weight ratios were prepared by co-precipitation method. The catalysts were characterized by X-ray diffraction, temperature programmed reduction, BET surface area, TPD of CO2 and N2O chemisorption. The catalysts were studied for selective hydrogenolysis of glycerol. The catalysts hydrogenolysis activity was related to the number available Cu sites on the support and moderate basicity of the catalysts. The catalyst with 20 %Cu-10 %ZrO2-MgO gave about 62 % of glycerol conversion with 97 % selectivity towards 1,2-propanediol. The effects of reaction temperature, hydrogen pressure, glycerol concentration and reaction time were also studied for the optimization of reaction conditions. A detailed kinetic study was also elucidated. [GRAPHICS]

引用

页码：1487 / 1496

页数：10

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