Cu-doping effect on structure and magnetic properties of Fe-doped ZnO powders

被引:41
作者
Liu, Huilian [1 ,2 ]
Yang, Jinghai [1 ,2 ]
Hua, Zhong [1 ,2 ]
Liu, Yang [1 ,2 ]
Yang, Lili [1 ,2 ]
Zhang, Yongjun [1 ,2 ]
Cao, Jian [1 ,2 ]
机构
[1] Jilin Normal Univ, Inst Condensed State Phys, Siping 136000, Peoples R China
[2] Jilin Normal Univ, Key Lab Funct Mat Phys & Chem, Minist Educ, Siping 136000, Peoples R China
关键词
Diluted magnetic semiconductors; Sol-gel method; Magnetic properties; Cu-doping; ROOM-TEMPERATURE FERROMAGNETISM; CODOPED ZNO; THIN-FILMS; CO; SEMICONDUCTORS; INJECTION;
D O I
10.1016/j.matchemphys.2010.10.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fe-doped and Cu, Fe co-doped ZnO diluted magnetic semiconductors powders were synthesized by sol-gel method. The x-ray diffraction (XRD) results showed that Zn0.97-xFe0.03CuxO (x <= 0.02) samples were single phase with the ZnO-like wurtzite structure. X-ray photoelectron spectroscopy (XPS) showed that Fe2+ and Fe3+ existed in Zn0.97Fe0.03O, while Fe2+, Fe3+ and Cu+, Cu2+ were found in Zr0.95Fe0.03Cu0.02O. Both Zn0.97Fe0.03O and Zn0.95Fe0.03Cd0.02O exhibited ferromagnetic performance at room temperature. But the Cu incorporation reduced the saturation magnetization of Fe-doped ZnO diluted magnetic semiconductors. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:656 / 659
页数:4
相关论文
共 23 条
[1]   Structure and photoluminescence properties of Fe-doped ZnO thin films [J].
Chen, A. J. ;
Wu, X. M. ;
Sha, Z. D. ;
Zhuge, L. J. ;
Meng, Y. D. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2006, 39 (22) :4762-4765
[2]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[3]   Injection and detection of a spin-polarized current in a light-emitting diode [J].
Fiederling, R ;
Keim, M ;
Reuscher, G ;
Ossau, W ;
Schmidt, G ;
Waag, A ;
Molenkamp, LW .
NATURE, 1999, 402 (6763) :787-790
[4]   Magnetic interactions in transition-metal-doped ZnO:: An ab initio study [J].
Gopal, Priya ;
Spaldin, Nicola A. .
PHYSICAL REVIEW B, 2006, 74 (09)
[5]   A key to room-temperature ferromagnetism in Fe-doped ZnO: Cu [J].
Han, SJ ;
Song, JW ;
Yang, CH ;
Park, SH ;
Park, JH ;
Jeong, YH ;
Rhie, KW .
APPLIED PHYSICS LETTERS, 2002, 81 (22) :4212-4214
[6]   Magnetic anisotropy in the ferromagnetic Cu-doped ZnO nanoneedles [J].
Herng, T. S. ;
Lau, S. P. ;
Yu, S. F. ;
Yang, H. Y. ;
Wang, L. ;
Tanemura, M. ;
Chen, J. S. .
APPLIED PHYSICS LETTERS, 2007, 90 (03)
[7]   Ferromagnetism in Fe-doped ZnO nanocrystals: Experiment and theory [J].
Karmakar, Debjani ;
Mandal, S. K. ;
Kadam, R. M. ;
Paulose, P. L. ;
Rajarajan, A. K. ;
Nath, T. K. ;
Das, A. K. ;
Dasgupta, I. ;
Das, G. P. .
PHYSICAL REVIEW B, 2007, 75 (14)
[8]   Enhancement of ferromagnetic properties in Zn1-xCoxO by additional Cu doping [J].
Lin, HT ;
Chin, TS ;
Shih, JC ;
Lin, SH ;
Hong, TM ;
Huang, RT ;
Chen, FR ;
Kai, JJ .
APPLIED PHYSICS LETTERS, 2004, 85 (04) :621-623
[9]   Ferromagnetism and exchange bias in Fe-doped ZnO nanocrystals [J].
Liu, Huilian ;
Yang, Jinghai ;
Zhang, Yongjun ;
Wang, Yaxin ;
Wei, Macibin .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (03) :1021-1023
[10]   Nature of magnetism in Co- and Mn-doped ZnO prepared by sol-gel technique [J].
Manivannan, A. ;
Dutta, P. ;
Glaspell, G. ;
Seehra, M. S. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (08)