Synthesis and Structural Characterization of New Zinc Amidinate Complexes

被引：52

作者：

Schmidt, Sarah ^{[1
]}

Schulz, Stephan ^{[1
]}

Blaeser, Dieter ^{[1
]}

Boese, Roland ^{[1
]}

Bolte, Michael ^{[2
]}

机构：

[1] Univ Duisburg Essen, Inst Inorgan Chem, D-45117 Essen, Germany

[2] Goethe Univ Frankfurt, Inst Inorgan Chem, D-60438 Frankfurt, Germany

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 22期

关键词：

ALPHA-DIIMINE LIGAND; BONDED COMPOUND; COORDINATION CHEMISTRY; LACTIDE POLYMERIZATION; CYCLOHEXENE OXIDE; CATIONIC ALUMINUM; CARBON-DIOXIDE; ZN; MAGNESIUM; COPOLYMERIZATION;

D O I：

10.1021/om1008549

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and reactivity of heteroleptic zinc complexes of the type LZnX (X = Me, I) containing amidinate ligands L of varying steric bulk were investigated. Complexes of the type LZnMe, which were obtained from the homoleptic complexes L2Zn upon reaction with ZnMe2, react with iodine with subsequent formation of LZnI. Single-crystal X-ray structures of the amidinate zinc complexes [{MeC(Ni-Pr)(2)}ZnMe](2), 1, [{MeC(Ni-Pr)(2)}ZnI](2)LiI(OEt)(2),3, [t-BuC(NDiPP)(2)]ZnMe, 5, [t-BuC(NDipp)(2)]ZnMe(t-BuPy), 6, [{t-BuC(NDiPP)(2)}Zn(mu-I)](2),7, and [t-BuC{N(H)Dipp}(2)][Al{OC(CF3)(3)}(4)],8, are reported.

引用

页码：6097 / 6103

页数：7

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