C(sp3)-C(sp3) Bond Breaking in Methylenecyclopropanes Involving a AuI/AuIII Catalytic Cycle

被引：13
|
作者：
Zhang, Di-Han [1 ]
Dai, Lun-Zhi [1 ]
Shi, Min [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 2010卷 / 28期
基金：
中国国家自然科学基金;
关键词：
Gold; C-C bond activation; Methylenecyclopropanes; UNIQUE TETRASUBSTITUTED ALKENE; HOMOGENEOUS GOLD CATALYSIS; HETEROCYCLES; BICYCLOPROPYLIDENE; ALKYNES; CARBOCYCLES; ACTIVATION; ESTERS; LEWIS;
D O I：
10.1002/ejoc.201000765
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gold(I) can catalyze the diacetoxylation of methylenecyclopropanes to produce the corresponding diacetoxylated products in moderate to good yields in acetic acid in the presence of iodosobenzene diacetate via C-C bond breaking under mild condition.
引用
收藏
页码：5454 / 5459
页数：6
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