Seedless synthesis of octahedral gold nanoparticles in condensed surfactant phase

被引:32
作者
Cao, Cuong [1 ]
Park, Sungho [2 ,3 ]
Sim, Sang Jun [1 ]
机构
[1] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Dept Chem, BK21 Sch Chem Mat Sci, Suwon 440746, South Korea
[3] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol, Suwon 440746, South Korea
关键词
template-directed synthesis; non-seeding process; H2O2-dependent growth; octahedra; gold nanoparticles;
D O I
10.1016/j.jcis.2008.03.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report a seedless synthetic method of gold octahedral nanoparticles in an aqueous phase. Eight facets with {1 1 1} crystalline structures of octahedral nanoparticles could be formed in an aqueous medium when the gold salt was reduced by ascorbic acid at room temperature in the presence of cetyltrimethylammonium bromide as a shape-inducing agent, and hydrogen peroxide as a reaction promoter. The growth kinetics and surface crystalline structures were characterized by UV-vis spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy. (C) 2008 Elsevier Inc. All rights reserved.
引用
收藏
页码:152 / 157
页数:6
相关论文
共 34 条
[1]   High-yield synthesis of multi-branched urchin-like gold nanoparticles [J].
Bakr, Osman M. ;
Wunsch, Benjamin H. ;
Stellacci, Francesco .
CHEMISTRY OF MATERIALS, 2006, 18 (14) :3297-3301
[2]   Nanoparticles with Raman spectroscopic fingerprints for DNA and RNA detection [J].
Cao, YWC ;
Jin, RC ;
Mirkin, CA .
SCIENCE, 2002, 297 (5586) :1536-1540
[3]   Integration of colloidal nanocrystals into lithographically patterned devices [J].
Cui, Y ;
Bjork, MT ;
Liddle, JA ;
Sonnichsen, C ;
Boussert, B ;
Alivisatos, AP .
NANO LETTERS, 2004, 4 (06) :1093-1098
[4]   A unified view of propagating and localized surface plasmon resonance biosensors [J].
Haes, AJ ;
Van Duyne, RP .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2004, 379 (7-8) :920-930
[5]   Using solution-phase nanoparticles, surface-confined nanoparticle arrays and single nanoparticles as biological sensing platforms [J].
Haes, AJ ;
Stuart, DA ;
Nie, SM ;
Van Duyne, RP .
JOURNAL OF FLUORESCENCE, 2004, 14 (04) :355-367
[6]  
IGLESIAS AS, 2006, ADV MATER, V18, P2529
[7]   Gold nanoparticles prepared by sonochemical method in thiol-functionalized ionic liquid [J].
Jin, Yong ;
Wang, Pingjun ;
Yin, Donghong ;
Liu, Jianfu ;
Qin, Liangsheng ;
Yu, Ningya ;
Xie, Guoyong ;
Li, Biaomo .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 302 (1-3) :366-370
[8]   Growth and form of gold nanorods prepared by seed-mediated, surfactant-directed synthesis [J].
Johnson, CJ ;
Dujardin, E ;
Davis, SA ;
Murphy, CJ ;
Mann, S .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (06) :1765-1770
[9]   Photophysical, photochemical and photocatalytic aspects of metal nanoparticles [J].
Kamat, PV .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (32) :7729-7744
[10]   The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment [J].
Kelly, KL ;
Coronado, E ;
Zhao, LL ;
Schatz, GC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (03) :668-677