Micellar catalysis in aqueous-ionic liquid systems

被引:75
作者
Bica, Katharina [1 ]
Gaertner, Peter [1 ]
Gritsch, Philipp J. [1 ]
Ressmann, Anna K. [1 ]
Schroeder, Christian [2 ]
Zirbs, Ronald [3 ]
机构
[1] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria
[2] Univ Vienna, Inst Computat Biol Chem, A-1090 Vienna, Austria
[3] Univ Nat Resources & Life Sci, Grp Biol Inspired Mat, Inst Nanobiotechnol DNBT, A-1190 Vienna, Austria
关键词
DIELS-ALDER REACTIONS; AGGREGATION; SOLVENT;
D O I
10.1039/c2cc31503c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present the application of ionic liquid-aqueous micellar solutions as reaction media for Diels-Alder reaction and found that reaction rates could be significantly increased compared to the reaction in water.
引用
收藏
页码:5013 / 5015
页数:3
相关论文
共 30 条
[1]   The role of hydrogen bonding in controlling the selectivity of Diels-Alder reactions in room-temperature ionic liquids [J].
Aggarwal, A ;
Lancaster, NL ;
Sethi, AR ;
Welton, T .
GREEN CHEMISTRY, 2002, 4 (05) :517-520
[2]   Speciation of chloroindate(III) ionic liquids [J].
Apperley, David C. ;
Hardacre, Christopher ;
Licence, Peter ;
Murphy, Richard W. ;
Plechkova, Natalia V. ;
Seddon, Kenneth R. ;
Srinivasan, Geetha ;
Swadzba-Kwasny, Malgorzata ;
Villar-Garcia, Ignacio J. .
DALTON TRANSACTIONS, 2010, 39 (37) :8679-8687
[3]   Initial Stages of Aggregation in Aqueous Solutions of Ionic Liquids: Molecular Dynamics Studies [J].
Bhargava, B. L. ;
Klein, Michael L. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (28) :9499-9505
[4]  
Bica K, 2011, CURR ORG SYNTH, V8, P824
[5]   Metal-containing ionic liquids as efficient catalysts for hydroxymethylation in water [J].
Bica, Katharina ;
Gaertner, Peter .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (20) :3453-3456
[6]   Self-aggregation of ionic liquids: micelle formation in aqueous solution [J].
Blesic, Marijana ;
Marques, Maria Helena ;
Plechkova, Natalia V. ;
Seddon, Kenneth R. ;
Rebelo, Luis Paulo N. ;
Lopes, Antonio .
GREEN CHEMISTRY, 2007, 9 (05) :481-490
[7]   New catanionic surfactants based on 1-alkyl-3-methylimidazolium alkylsulfonates, [CnH2n+1mim][CmH2m+1SO3]: mesomorphism and aggregation [J].
Blesic, Marijana ;
Swadzba-Kwasny, Magorzata ;
Holbrey, John D. ;
Canongia Lopes, Jose N. ;
Seddon, Kenneth R. ;
Rebelo, Luis Paulo N. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (21) :4260-4268
[8]   DIELS-ALDER REACTIONS IN AQUEOUS-SOLUTIONS - ENFORCED HYDROPHOBIC INTERACTIONS BETWEEN DIENE AND DIENOPHILE [J].
BLOKZIJL, W ;
BLANDAMER, MJ ;
ENGBERTS, JBFN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (11) :4241-4246
[9]   Aggregation behavior of aqueous solutions of ionic liquids [J].
Bowers, J ;
Butts, CP ;
Martin, PJ ;
Vergara-Gutierrez, MC ;
Heenan, RK .
LANGMUIR, 2004, 20 (06) :2191-2198
[10]   The dramatic acceleration effect of imidazolium ionic liquids on electron transfer reactions [J].
Choi, Doo Seong ;
Kim, Dong Hyun ;
Shin, Ueon Sang ;
Deshmukh, Ravindra R. ;
Lee, Sang-Gi ;
Song, Choong Eui .
CHEMICAL COMMUNICATIONS, 2007, (33) :3467-3469